Zeolitic imidazole framework-67 as an efficient heterogeneous catalyst for the conversion of CO2 to cyclic carbonates

Bibimaryam Mousavi, Somboon Chaemchuen, Behrooz Moosavi, Zhixiong Luo, Nadia Gholampour, Francis Walter Cornelius Verpoort

Результат исследований: Материалы для журналаСтатья

49 Цитирования (Scopus)

Аннотация

Zeolitic imidazole framework (ZIF)-67 is an efficient heterogeneous catalyst for the cycloaddition of carbon dioxide to epoxides to afford cyclic carbonates. In this work, ZIF-67 was synthesized by a simple and straightforward method at room temperature. The coupling reaction in the presence of ZIF-67 without any co-catalyst or solvent was studied under different conditions. The reaction conversion was more than 99% and the selectivity toward chloropropene carbonate was considerably higher (>99%) than the previously reported ZIF-8. Moreover, the ZIF-67 catalyst could be recycled at least four times without noticeable loss of catalytic activity.

Язык оригиналаАнглийский
Страницы (с-по)5170-5176
Число страниц7
ЖурналNew Journal of Chemistry
Том40
Номер выпуска6
DOI
СостояниеОпубликовано - 2016

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Materials Chemistry

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