X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes

Аннотация

We have established that the total electron density on the chlorine atoms in SnCl₄L₂ complexes remains virtually unchanged compared with the original acceptor in strong complexes, decreases with weak complexes, and markedly increases in all the studied TiCl₄L₂ complexes. We show that the negative charge decreases on the chlorine atoms in the acceptor part of SnCl₄L₂ trans complexes, with square planar SnCl₄, compared with the original tetrahedral configuration.

Язык оригинала	Английский
Страницы (с-по)	2314-2317
Число страниц	4
Журнал	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Том	38
Номер выпуска	11
DOI	https://doi.org/10.1007/BF01168077
Состояние	Опубликовано - ноя 1989

ASJC Scopus subject areas

Chemistry(all)

Доступ к документу

10.1007/BF01168077

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Цитировать

Dolenko, G. N., Poleshchuk, O. K., Elin, V. P., Litvin, A. L., Udachin, I. V., & Ivanovskii, A. L. (1989). X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 38(11), 2314-2317. https://doi.org/10.1007/BF01168077

X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes. / Dolenko, G. N.; Poleshchuk, O. Kh; Elin, V. P.; Litvin, A. L.; Udachin, I. V.; Ivanovskii, A. L.

В: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Том 38, № 11, 11.1989, стр. 2314-2317.

Результат исследований: Материалы для журнала › Статья

Dolenko, GN, Poleshchuk, OK, Elin, VP, Litvin, AL, Udachin, IV & Ivanovskii, AL 1989, 'X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes', Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, том. 38, № 11, стр. 2314-2317. https://doi.org/10.1007/BF01168077

Dolenko GN, Poleshchuk OK, Elin VP, Litvin AL, Udachin IV, Ivanovskii AL. X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1989 Нояб.;38(11):2314-2317. https://doi.org/10.1007/BF01168077

Dolenko, G. N. ; Poleshchuk, O. Kh ; Elin, V. P. ; Litvin, A. L. ; Udachin, I. V. ; Ivanovskii, A. L. / X-ray fluorescent spectroscopy study of the charge state of heteroatoms in organic compounds of third row elements. 8. Tin chloride and its complexes. В: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1989 ; Том 38, № 11. стр. 2314-2317.

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abstract = "We have established that the total electron density on the chlorine atoms in SnCl4L2 complexes remains virtually unchanged compared with the original acceptor in strong complexes, decreases with weak complexes, and markedly increases in all the studied TiCl4L2 complexes. We show that the negative charge decreases on the chlorine atoms in the acceptor part of SnCl4L2 trans complexes, with square planar SnCl4, compared with the original tetrahedral configuration.",

author = "Dolenko, {G. N.} and Poleshchuk, {O. Kh} and Elin, {V. P.} and Litvin, {A. L.} and Udachin, {I. V.} and Ivanovskii, {A. L.}",

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AU - Elin, V. P.

AU - Litvin, A. L.

AU - Udachin, I. V.

AU - Ivanovskii, A. L.

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AB - We have established that the total electron density on the chlorine atoms in SnCl4L2 complexes remains virtually unchanged compared with the original acceptor in strong complexes, decreases with weak complexes, and markedly increases in all the studied TiCl4L2 complexes. We show that the negative charge decreases on the chlorine atoms in the acceptor part of SnCl4L2 trans complexes, with square planar SnCl4, compared with the original tetrahedral configuration.

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