Wet peroxide oxidation of phenol over Cu-ZSM-5 catalyst in a flow reactor. Kinetics and diffusion study

Oxana P. Taran, Andrey Nikolaevich Zagoruiko, Artemiy B. Ayusheev, Svetlana A. Yashnik, Roman V. Prihod'ko, Zinfer R. Ismagilov, Vladislav V. Goncharuk, Valentin N. Parmon

Результат исследований: Материалы для журналаСтатья

22 Цитирования (Scopus)


The wet peroxide oxidation of phenol over the extruded 1.5%Cu/(80%H-ZSM-5 + 20%Al2O3) catalysts of the different geometric forms and sizes (cylinders with diameters 1, 2, 3 mm, trefoils, spheres and monoliths with size of channels 1.0 × 1.0, 1.5 × 1.5 mm) was studied in a flow reactor. The geometric form and size of the catalyst granules exert a pronounced effect on the apparent kinetics of the process. The highest efficiency toward phenol destruction was observed for the catalysts with a greater geometric surface area (trefoils and monolith with high channel density). The conversions of phenol and TOC at flow rate 5 mL min-1 equal to 100 and ∼90% were achieved over these catalysts. Application of the spherical shape catalyst with lowest geometric surface gave only 80% conversion of phenol at the same reaction conditions. The proposed mathematical model of the process, accounting for internal and external diffusion limitations on the base of the pseudo-first order simplification of the apparent kinetic rates, provide reasonably accurate description of the experimental data and reproducing all important process regularities.

Язык оригиналаАнглийский
Страницы (с-по)108-115
Число страниц8
ЖурналChemical Engineering Journal
СостояниеОпубликовано - 15 дек 2015


ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)
  • Industrial and Manufacturing Engineering
  • Environmental Chemistry


Taran, O. P., Zagoruiko, AN., Ayusheev, A. B., Yashnik, S. A., Prihod'ko, R. V., Ismagilov, Z. R., Goncharuk, V. V., & Parmon, V. N. (2015). Wet peroxide oxidation of phenol over Cu-ZSM-5 catalyst in a flow reactor. Kinetics and diffusion study. Chemical Engineering Journal, 282, 108-115. https://doi.org/10.1016/j.cej.2015.02.064