Water Oxidation by In Situ Generated [RuII(OH2)(NCNHCO)(pic)2]+

Wei Su, Kui Zhou, Fanglin Cai, Cheng Chen, Bibimaryam Mousavi, Somboon Chaemchuen, Francis Verpoort

Результат исследований: Материалы для журналаСтатья

2 Цитирования (Scopus)

Аннотация

A dinuclear ruthenium complex [RuII(NCNHCO)(pic)2]2 2+ (2) was firstly prepared and characterized spectroscopically and electrochemically. Instead of the conventional ligand exchange, complex 2 dissociates in situ to afford two single-site Ru aqua complexes, [RuII(OH2)(NCNHCO)(pic)2]+, which mediates water oxidation through proton-coupled electron transfer events. In electrokinetic studies, complex 2 demonstrated a TOF of 150.3 s−1 comparable to those state-of-the-art catalysts at neutral conditions. TONs of 2173 and 217 were attained in chemical and photochemical water oxidation when 2 was used as a catalyst, exhibiting good stability. Notably, a TOF of 1.3 s−1 was achieved at CAN-driven water oxidation, which outperformed most of the reported single-site Ru complexes, indicating that complex 2 is one of most active water oxidation catalysts (WOCs) to date. The unique coordination configuration and outstanding catalytic performance of complex 2 might shed light on the design of novel molecular WOCs.

Язык оригиналаАнглийский
Страницы (с-по)2304-2310
Число страниц7
ЖурналChemistry - An Asian Journal
Том12
Номер выпуска17
DOI
СостояниеОпубликовано - 5 сен 2017

ASJC Scopus subject areas

  • Chemistry(all)

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