Vibration-rotation polarizability operator for non-linear X 2Y - type molecules and the ro-vibrational Raman cross sections calculation of water molecule

V. I. Starikov, A. E. Protasevich

    Результат исследований: Материалы для книги/типы отчетовМатериалы для конференции

    Аннотация

    The expression for the second - order transformed polarizability operator for non-linear X 2Y - type molecules is derived using the method of contact transformation. This operator is used for the calculation of ro-vibrational Raman cross sections of the H 2O molecule. It is shown that the ro-vibrational correction terms change the integral intensity of pure rotational lines significantly and the v 2 band slightly. The vibrational dependence of the mean polarizability of H 2O is analyzed in the calculation of integral intensity of one and two quantum bands.

    Язык оригиналаАнглийский
    Название основной публикацииProceedings of SPIE - The International Society for Optical Engineering
    РедакторыL.N. Sinitsa, S.N. Mikhailenko
    Страницы148-155
    Число страниц8
    Том5311
    СостояниеОпубликовано - 2004
    Событие14th Symposium on High-Resolution Molecular Spectroscopy - Krasnoyarsk, Российская Федерация
    Продолжительность: 6 июл 200311 июл 2003

    Другое

    Другое14th Symposium on High-Resolution Molecular Spectroscopy
    СтранаРоссийская Федерация
    ГородKrasnoyarsk
    Период6.7.0311.7.03

    ASJC Scopus subject areas

    • Electrical and Electronic Engineering
    • Condensed Matter Physics

    Fingerprint Подробные сведения о темах исследования «Vibration-rotation polarizability operator for non-linear X <sub>2</sub>Y - type molecules and the ro-vibrational Raman cross sections calculation of water molecule». Вместе они формируют уникальный семантический отпечаток (fingerprint).

  • Цитировать

    Starikov, V. I., & Protasevich, A. E. (2004). Vibration-rotation polarizability operator for non-linear X 2Y - type molecules and the ro-vibrational Raman cross sections calculation of water molecule. В L. N. Sinitsa, & S. N. Mikhailenko (Ред.), Proceedings of SPIE - The International Society for Optical Engineering (Том 5311, стр. 148-155)