Transition-metal-free catalytic synthesis of 1,5-diaryl-1,2,3-triazoles

Sen W. Kwok, Joseph R. Fotsing, Rebecca J. Fraser, Valentin O. Rodionov, Valery V. Fokin

Результат исследований: Материалы для журнала › Статья

Аннотация

Figure Presented. 1,5-Diarylsubstituted 1,2,3-triazoles are formed in high yield from aryl azides and terminal alkynes in DMSO in the presence of catalytic tetraalkylammonium hydroxide. The reaction is experimentally simple, does not require a transition-metal catalyst, and is not sensitive to atmospheric oxygen and moisture.

Язык оригинала	Английский
Страницы (с-по)	4217-4219
Число страниц	3
Журнал	Organic Letters
Том	12
Номер выпуска	19
DOI	https://doi.org/10.1021/ol101568d
Состояние	Опубликовано - 1 окт 2010
Опубликовано для внешнего пользования	Да

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ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Biochemistry

Цитировать

Kwok, S. W., Fotsing, J. R., Fraser, R. J., Rodionov, V. O., & Fokin, V. V. (2010). Transition-metal-free catalytic synthesis of 1,5-diaryl-1,2,3-triazoles. Organic Letters, 12(19), 4217-4219. https://doi.org/10.1021/ol101568d

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abstract = "Figure Presented. 1,5-Diarylsubstituted 1,2,3-triazoles are formed in high yield from aryl azides and terminal alkynes in DMSO in the presence of catalytic tetraalkylammonium hydroxide. The reaction is experimentally simple, does not require a transition-metal catalyst, and is not sensitive to atmospheric oxygen and moisture.",

author = "Kwok, {Sen W.} and Fotsing, {Joseph R.} and Fraser, {Rebecca J.} and Rodionov, {Valentin O.} and Fokin, {Valery V.}",

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AU - Kwok, Sen W.

AU - Fotsing, Joseph R.

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AU - Rodionov, Valentin O.

AU - Fokin, Valery V.

PY - 2010/10/1

Y1 - 2010/10/1

N2 - Figure Presented. 1,5-Diarylsubstituted 1,2,3-triazoles are formed in high yield from aryl azides and terminal alkynes in DMSO in the presence of catalytic tetraalkylammonium hydroxide. The reaction is experimentally simple, does not require a transition-metal catalyst, and is not sensitive to atmospheric oxygen and moisture.

AB - Figure Presented. 1,5-Diarylsubstituted 1,2,3-triazoles are formed in high yield from aryl azides and terminal alkynes in DMSO in the presence of catalytic tetraalkylammonium hydroxide. The reaction is experimentally simple, does not require a transition-metal catalyst, and is not sensitive to atmospheric oxygen and moisture.

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Доступ к документу

10.1021/ol101568d