Transient optical absorption and luminescence of lithium triborate LiB3O5

I. N. Ogorodnikov, V. Yu Yakovlev, L. I. Isaenko

Результат исследований: Материалы для журналаСтатья

15 Цитирования (Scopus)

Выдержка

The transient optical absorption and luminescence of LiB3O5 (LBO) nonlinear crystals in the visible and UV spectral ranges were studied. Measurements made using absorption optical spectroscopy with ns-scale time resolution revealed that the transient optical absorption (TOA) in LBO originates from optical transitions in hole centers and that the kinetics of optical density relaxation are rate-limited by interdefect nonradiative tunneling recombination involving these hole centers and the Li0 electronic centers, which represent neutral lithium atoms. At 290 K, the Li0 centers can migrate in a thermally stimulated, one-dimensional manner, a process which is not accompanied by carrier delocalization into the conduction or valence band. It is shown that the pulsed LBO cathodoluminescence kinetics is rate-limited by a recombination process involving two competing valence-band-mediated hole centers and shallow B2+ electronic centers. The radiative recombination accounts for the characteristic σ-polarized LBO luminescence in the 4.0-eV region.

Язык оригиналаАнглийский
Страницы (с-по)845-853
Число страниц9
ЖурналPhysics of the Solid State
Том45
Номер выпуска5
DOI
СостояниеОпубликовано - 1 мая 2003

Отпечаток

Valence bands
Light absorption
Luminescence
Lithium
optical absorption
lithium
luminescence
Kinetics
Optical transitions
Density (optical)
Cathodoluminescence
Conduction bands
Atoms
Crystals
valence
optical density
kinetics
radiative recombination
cathodoluminescence
electronics

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Цитировать

Transient optical absorption and luminescence of lithium triborate LiB3O5. / Ogorodnikov, I. N.; Yakovlev, V. Yu; Isaenko, L. I.

В: Physics of the Solid State, Том 45, № 5, 01.05.2003, стр. 845-853.

Результат исследований: Материалы для журналаСтатья

Ogorodnikov, I. N. ; Yakovlev, V. Yu ; Isaenko, L. I. / Transient optical absorption and luminescence of lithium triborate LiB3O5. В: Physics of the Solid State. 2003 ; Том 45, № 5. стр. 845-853.
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