Time dependence of the NMR line shape for systems with chemical exchange in a zero saturation limit

S. P. Babailov, D. A. Mainichev

Результат исследований: Материалы для журналаСтатья

Аннотация

An expression has been derived for the time dependence of the NMR line shape for systems with many-site chemical exchange in the absence of spin-spin coupling, in a zero saturation limit. The dynamics of variation of the NMR line shape with time is considered in detail for the case of two-site chemical exchange. Mathematica programs have been designed for numerical simulation of the NMR spectra of chemical exchange systems. The analytical expressions obtained are useful for NMR line shape simulations for systems with photoinduced chemical exchange.

Язык оригиналаАнглийский
Страницы (с-по)442-446
Число страниц5
ЖурналJournal of Structural Chemistry
Том47
Номер выпуска3
DOI
СостояниеОпубликовано - мая 2006
Опубликовано для внешнего пользованияДа

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ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

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