The study of the electronic structure of SbCl5L and SnCl4L2 complexes by the PM3 method

Аннотация

The electronic structures of the SbCl₅L and SnCl₄L₂ complexes are studied by the PM3 method. The results are compared with the relevant ³⁵Cl NQR, ¹²¹Sb NQR, and Mossbauer data. The calculated nuclear quadrupole coupling constants agree well with their experimental values. The energies of formation of the donor-acceptor bonds are correlated with the amounts of transferred electron density. The observed correlation relationships are different for the cis and trans complexes.

Язык оригинала	Английский
Страницы (с-по)	698-702
Число страниц	5
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	23
Номер выпуска	10
Состояние	Опубликовано - 1 окт 1997

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

Другие файлы и ссылки

Fingerprint Подробные сведения о темах исследования «The study of the electronic structure of SbCl5L and SnCl4L2 complexes by the PM3 method». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

The study of the electronic structure of SbCl₅L and SnCl₄L₂ complexes by the PM3 method. / Poleshchuk, O. Kh; Latoshinska, I.; Koput, Ya.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 23, № 10, 01.10.1997, стр. 698-702.

Результат исследований: Материалы для журнала › Статья › рецензирование

@article{e7382f3d976941b496c5e8371e8b77c3,

title = "The study of the electronic structure of SbCl5L and SnCl4L2 complexes by the PM3 method",

abstract = "The electronic structures of the SbCl5L and SnCl4L2 complexes are studied by the PM3 method. The results are compared with the relevant 35Cl NQR, 121Sb NQR, and Mossbauer data. The calculated nuclear quadrupole coupling constants agree well with their experimental values. The energies of formation of the donor-acceptor bonds are correlated with the amounts of transferred electron density. The observed correlation relationships are different for the cis and trans complexes.",

author = "Poleshchuk, {O. Kh} and I. Latoshinska and Ya Koput",

year = "1997",

month = oct,

day = "1",

language = "English",

volume = "23",

pages = "698--702",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "10",

}

TY - JOUR

T1 - The study of the electronic structure of SbCl5L and SnCl4L2 complexes by the PM3 method

AU - Poleshchuk, O. Kh

AU - Latoshinska, I.

AU - Koput, Ya

PY - 1997/10/1

Y1 - 1997/10/1

N2 - The electronic structures of the SbCl5L and SnCl4L2 complexes are studied by the PM3 method. The results are compared with the relevant 35Cl NQR, 121Sb NQR, and Mossbauer data. The calculated nuclear quadrupole coupling constants agree well with their experimental values. The energies of formation of the donor-acceptor bonds are correlated with the amounts of transferred electron density. The observed correlation relationships are different for the cis and trans complexes.

AB - The electronic structures of the SbCl5L and SnCl4L2 complexes are studied by the PM3 method. The results are compared with the relevant 35Cl NQR, 121Sb NQR, and Mossbauer data. The calculated nuclear quadrupole coupling constants agree well with their experimental values. The energies of formation of the donor-acceptor bonds are correlated with the amounts of transferred electron density. The observed correlation relationships are different for the cis and trans complexes.

UR - http://www.scopus.com/inward/record.url?scp=27644579718&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=27644579718&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:27644579718

VL - 23

SP - 698

EP - 702

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 10

ER -