The study of the electronic structure of SbCl5L and SnCl4L2 complexes by the PM3 method

O. Kh Poleshchuk, I. Latoshinska, Ya Koput

    Результат исследований: Материалы для журналаСтатья

    Выдержка

    The electronic structures of the SbCl5L and SnCl4L2 complexes are studied by the PM3 method. The results are compared with the relevant 35Cl NQR, 121Sb NQR, and Mossbauer data. The calculated nuclear quadrupole coupling constants agree well with their experimental values. The energies of formation of the donor-acceptor bonds are correlated with the amounts of transferred electron density. The observed correlation relationships are different for the cis and trans complexes.

    Язык оригиналаАнглийский
    Страницы (с-по)698-702
    Число страниц5
    ЖурналRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
    Том23
    Номер выпуска10
    СостояниеОпубликовано - 1 окт 1997

    Отпечаток

    Electronic structure
    Carrier concentration

    ASJC Scopus subject areas

    • Chemistry(all)
    • Chemical Engineering(all)

    Цитировать

    The study of the electronic structure of SbCl5L and SnCl4L2 complexes by the PM3 method. / Poleshchuk, O. Kh; Latoshinska, I.; Koput, Ya.

    В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 23, № 10, 01.10.1997, стр. 698-702.

    Результат исследований: Материалы для журналаСтатья

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