The structure of a new copper(II) complex with 3-methyl-5- carboxylatopyrazole

L. G. Lavernova, E. V. Peresypkina, A. S. Zhilin, O. G. Shakirova, M. N. Novikov, S. F. Vasilevskii

Результат исследований: Материалы для журналаСтатья

Выдержка

Molecular and crystal structures of a new complex compound of copper(II) with 3-methyl-5-carboxylatopyrazole (CH3PzCOO-) with the composition Cu(CH3PzCOO)2•H2O have been determined by single crystal XRD. It has been demonstrated that the carboxylate ion performs the bridging tridentate function. In the equatorial plane coordination occurs through the pyridine N atom of the pyrazole and one of O atoms of the carboxylate group yielding a five-membered metallocycle CuNOC 2. The second O atom of one of the ligands is bound to the neighboring copper(II) ion affording an infinite linear chain. The coordination polyhedron of the copper atom is a square pyramid, coordination core CuN 2O3.

Язык оригиналаАнглийский
Страницы (с-по)1104-1107
Число страниц4
ЖурналJournal of Structural Chemistry
Том49
Номер выпуска6
DOI
СостояниеОпубликовано - 1 ноя 2008
Опубликовано для внешнего пользованияДа

Отпечаток

Copper
copper
Atoms
carboxylates
atoms
Ions
complex compounds
pyramids
polyhedrons
Pyridine
Molecular structure
pyridines
ions
molecular structure
Crystal structure
Ligands
Single crystals
ligands
crystal structure
single crystals

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Цитировать

Lavernova, L. G., Peresypkina, E. V., Zhilin, A. S., Shakirova, O. G., Novikov, M. N., & Vasilevskii, S. F. (2008). The structure of a new copper(II) complex with 3-methyl-5- carboxylatopyrazole. Journal of Structural Chemistry, 49(6), 1104-1107. https://doi.org/10.1007/s10947-008-0185-2

The structure of a new copper(II) complex with 3-methyl-5- carboxylatopyrazole. / Lavernova, L. G.; Peresypkina, E. V.; Zhilin, A. S.; Shakirova, O. G.; Novikov, M. N.; Vasilevskii, S. F.

В: Journal of Structural Chemistry, Том 49, № 6, 01.11.2008, стр. 1104-1107.

Результат исследований: Материалы для журналаСтатья

Lavernova, LG, Peresypkina, EV, Zhilin, AS, Shakirova, OG, Novikov, MN & Vasilevskii, SF 2008, 'The structure of a new copper(II) complex with 3-methyl-5- carboxylatopyrazole', Journal of Structural Chemistry, том. 49, № 6, стр. 1104-1107. https://doi.org/10.1007/s10947-008-0185-2
Lavernova, L. G. ; Peresypkina, E. V. ; Zhilin, A. S. ; Shakirova, O. G. ; Novikov, M. N. ; Vasilevskii, S. F. / The structure of a new copper(II) complex with 3-methyl-5- carboxylatopyrazole. В: Journal of Structural Chemistry. 2008 ; Том 49, № 6. стр. 1104-1107.
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AU - Lavernova, L. G.

AU - Peresypkina, E. V.

AU - Zhilin, A. S.

AU - Shakirova, O. G.

AU - Novikov, M. N.

AU - Vasilevskii, S. F.

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N2 - Molecular and crystal structures of a new complex compound of copper(II) with 3-methyl-5-carboxylatopyrazole (CH3PzCOO-) with the composition Cu(CH3PzCOO)2•H2O have been determined by single crystal XRD. It has been demonstrated that the carboxylate ion performs the bridging tridentate function. In the equatorial plane coordination occurs through the pyridine N atom of the pyrazole and one of O atoms of the carboxylate group yielding a five-membered metallocycle CuNOC 2. The second O atom of one of the ligands is bound to the neighboring copper(II) ion affording an infinite linear chain. The coordination polyhedron of the copper atom is a square pyramid, coordination core CuN 2O3.

AB - Molecular and crystal structures of a new complex compound of copper(II) with 3-methyl-5-carboxylatopyrazole (CH3PzCOO-) with the composition Cu(CH3PzCOO)2•H2O have been determined by single crystal XRD. It has been demonstrated that the carboxylate ion performs the bridging tridentate function. In the equatorial plane coordination occurs through the pyridine N atom of the pyrazole and one of O atoms of the carboxylate group yielding a five-membered metallocycle CuNOC 2. The second O atom of one of the ligands is bound to the neighboring copper(II) ion affording an infinite linear chain. The coordination polyhedron of the copper atom is a square pyramid, coordination core CuN 2O3.

KW - Complex

KW - Copper

KW - Crystal and molecular structure

KW - Pyrazole derivatives

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