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The infrared spectrum of doubly deuterated methane CH2D2 has been recorded in the region from 1900 to 2400 cm-1 at almost Doppler-limited resolution by using two high-resolution Fourier transform spectrometers. The vibrational bands observed include 2ν4, ν4 + ν7, 2ν7, ν2, ν8, ν4 + ν9, and ν7 + ν9, which were analyzed by taking into account Coriolis and Fermi interactions among them and also those with ν4 + ν5, ν3 + ν7, and ν5 + ν7. Most of the centrifugal distortion constants were constrained to appropriate values, while the vibrational term value and three rotational constants in each of the seven excited states were adjusted along with Coriolis and Fermi interaction parameters by the least-squares analysis of the observed spectrum. The vibration-rotation interaction constants αs thus determined for the ν2 and ν8 states were combined with those of other fundamental states already published to calculate the equilibrium C-H distance.
| Язык оригинала | Английский |
|---|---|
| Страницы (с-по) | 423-432 |
| Число страниц | 10 |
| Журнал | Journal of Molecular Spectroscopy |
| Том | 180 |
| Номер выпуска | 2 |
| DOI | |
| Состояние | Опубликовано - 1 янв 1996 |
Отпечаток
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
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The high-resolution fourier transform spectrum of dideuterated methane CH2D2 in the region between 1900 and 2400 cm-1 . / Ulenikov, Oleg N.; Hirota, Eizi; Akiyama, Mitsuru; Alanko, S.; Koivusaari, M.; Anttila, R.; Guelachvili, G.; Tolchenov, R. N.
В: Journal of Molecular Spectroscopy, Том 180, № 2, 01.01.1996, стр. 423-432.Результат исследований: Материалы для журнала › Статья
}
TY - JOUR
T1 - The high-resolution fourier transform spectrum of dideuterated methane CH2D2 in the region between 1900 and 2400 cm-1
AU - Ulenikov, Oleg N.
AU - Hirota, Eizi
AU - Akiyama, Mitsuru
AU - Alanko, S.
AU - Koivusaari, M.
AU - Anttila, R.
AU - Guelachvili, G.
AU - Tolchenov, R. N.
PY - 1996/1/1
Y1 - 1996/1/1
N2 - The infrared spectrum of doubly deuterated methane CH2D2 has been recorded in the region from 1900 to 2400 cm-1 at almost Doppler-limited resolution by using two high-resolution Fourier transform spectrometers. The vibrational bands observed include 2ν4, ν4 + ν7, 2ν7, ν2, ν8, ν4 + ν9, and ν7 + ν9, which were analyzed by taking into account Coriolis and Fermi interactions among them and also those with ν4 + ν5, ν3 + ν7, and ν5 + ν7. Most of the centrifugal distortion constants were constrained to appropriate values, while the vibrational term value and three rotational constants in each of the seven excited states were adjusted along with Coriolis and Fermi interaction parameters by the least-squares analysis of the observed spectrum. The vibration-rotation interaction constants αs thus determined for the ν2 and ν8 states were combined with those of other fundamental states already published to calculate the equilibrium C-H distance.
AB - The infrared spectrum of doubly deuterated methane CH2D2 has been recorded in the region from 1900 to 2400 cm-1 at almost Doppler-limited resolution by using two high-resolution Fourier transform spectrometers. The vibrational bands observed include 2ν4, ν4 + ν7, 2ν7, ν2, ν8, ν4 + ν9, and ν7 + ν9, which were analyzed by taking into account Coriolis and Fermi interactions among them and also those with ν4 + ν5, ν3 + ν7, and ν5 + ν7. Most of the centrifugal distortion constants were constrained to appropriate values, while the vibrational term value and three rotational constants in each of the seven excited states were adjusted along with Coriolis and Fermi interaction parameters by the least-squares analysis of the observed spectrum. The vibration-rotation interaction constants αs thus determined for the ν2 and ν8 states were combined with those of other fundamental states already published to calculate the equilibrium C-H distance.
UR - http://www.scopus.com/inward/record.url?scp=0343755076&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0343755076&partnerID=8YFLogxK
U2 - 10.1006/jmsp.1996.0266
DO - 10.1006/jmsp.1996.0266
M3 - Article
AN - SCOPUS:0343755076
VL - 180
SP - 423
EP - 432
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 2
ER -