The change of YSZ nanoparticles crystalline structure by powerful ultrasound activation

Результат исследований: Материалы для книги/типы отчетовМатериалы для конференции

Выдержка

The changes of phase composition in polymorphous ZrO2-5wt% Y2O3 (YSZ) nanopowder, size of crystallites and their microstrains induced by influence of powerful ultrasound activation (PUA) were studied by XRD techniques. It was shown that during the process of dry nanopowder sonication the part of tetragonal (t) phase transforms to cubic (c) one, its significant smaller part - to monoclinic (m) phase. With PUA power W increasing from O up to 3 kW the rise of apparent crystallite sizes (ACS) was observed for all the phases. Such increasing the ACS is unusual, as it would be expected decreasing the crystallite sizes because of the destroying action of PU-oscillations on crystalline substances. The analysis of ACS values versus phase composition showed that the smallest in size crystallites of t-phase (with the sizes about 10 nm) transfer to c-phase, therewith the average value of ACS of c-phase increases (but not ACS values themselves) at the expense of rise of crystallite amount with the sizes of ∼10 nm. The larger crystallites of t-phase (sizes about 40 nm) martensitely transfer to m-phase increasing the average value of ACS for this phase. As a result the t-phase loses the most part of its crystallites with small and medium sizes (from 10 up to 40 nm), and the average size of the rest of t-phase crystallites (but not the sizes by themselves) rises at increase of W. The essential influence of PUA on the relative crystallite microstrains in c-phase (consisting of small crystallites ∼10 nm) and slight influence on larger crystallites of m- and t-phases were observed.

Язык оригиналаАнглийский
Название основной публикацииProceedings - KORUS 2003: 7th Korea-Russia International Symposium on Science and Technology
ИздательInstitute of Electrical and Electronics Engineers Inc.
Страницы152-156
Число страниц5
Том1
ISBN (печатное издание)8978686176, 9788978686174
СостояниеОпубликовано - 2003
Событие7th Korea-Russia International Symposium on Science and Technology, KORUS 2003 - Ulsan, Республика Корея
Продолжительность: 28 июн 20036 июл 2003

Другое

Другое7th Korea-Russia International Symposium on Science and Technology, KORUS 2003
СтранаРеспублика Корея
ГородUlsan
Период28.6.036.7.03

Отпечаток

Sonication
Crystallite size
Crystallites
Nanoparticles
activation
Ultrasonics
Chemical activation
Crystalline materials
Values
Phase composition

ASJC Scopus subject areas

  • Building and Construction
  • Pollution
  • Biotechnology
  • Social Sciences (miscellaneous)
  • Medicine (miscellaneous)
  • Education

Цитировать

Khasanov, O., Dvilis, E., Polisadova, VV., & Bikbaeva, Z. G. (2003). The change of YSZ nanoparticles crystalline structure by powerful ultrasound activation. В Proceedings - KORUS 2003: 7th Korea-Russia International Symposium on Science and Technology (Том 1, стр. 152-156). [1222422] Institute of Electrical and Electronics Engineers Inc..

The change of YSZ nanoparticles crystalline structure by powerful ultrasound activation. / Khasanov, O.; Dvilis, E.; Polisadova, Valentina Valentinovna; Bikbaeva, Zulfa Gadilzanovna.

Proceedings - KORUS 2003: 7th Korea-Russia International Symposium on Science and Technology. Том 1 Institute of Electrical and Electronics Engineers Inc., 2003. стр. 152-156 1222422.

Результат исследований: Материалы для книги/типы отчетовМатериалы для конференции

Khasanov, O, Dvilis, E, Polisadova, VV & Bikbaeva, ZG 2003, The change of YSZ nanoparticles crystalline structure by powerful ultrasound activation. в Proceedings - KORUS 2003: 7th Korea-Russia International Symposium on Science and Technology. том. 1, 1222422, Institute of Electrical and Electronics Engineers Inc., стр. 152-156, Ulsan, Республика Корея, 28.6.03.
Khasanov O, Dvilis E, Polisadova VV, Bikbaeva ZG. The change of YSZ nanoparticles crystalline structure by powerful ultrasound activation. В Proceedings - KORUS 2003: 7th Korea-Russia International Symposium on Science and Technology. Том 1. Institute of Electrical and Electronics Engineers Inc. 2003. стр. 152-156. 1222422
Khasanov, O. ; Dvilis, E. ; Polisadova, Valentina Valentinovna ; Bikbaeva, Zulfa Gadilzanovna. / The change of YSZ nanoparticles crystalline structure by powerful ultrasound activation. Proceedings - KORUS 2003: 7th Korea-Russia International Symposium on Science and Technology. Том 1 Institute of Electrical and Electronics Engineers Inc., 2003. стр. 152-156
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abstract = "The changes of phase composition in polymorphous ZrO2-5wt{\%} Y2O3 (YSZ) nanopowder, size of crystallites and their microstrains induced by influence of powerful ultrasound activation (PUA) were studied by XRD techniques. It was shown that during the process of dry nanopowder sonication the part of tetragonal (t) phase transforms to cubic (c) one, its significant smaller part - to monoclinic (m) phase. With PUA power W increasing from O up to 3 kW the rise of apparent crystallite sizes (ACS) was observed for all the phases. Such increasing the ACS is unusual, as it would be expected decreasing the crystallite sizes because of the destroying action of PU-oscillations on crystalline substances. The analysis of ACS values versus phase composition showed that the smallest in size crystallites of t-phase (with the sizes about 10 nm) transfer to c-phase, therewith the average value of ACS of c-phase increases (but not ACS values themselves) at the expense of rise of crystallite amount with the sizes of ∼10 nm. The larger crystallites of t-phase (sizes about 40 nm) martensitely transfer to m-phase increasing the average value of ACS for this phase. As a result the t-phase loses the most part of its crystallites with small and medium sizes (from 10 up to 40 nm), and the average size of the rest of t-phase crystallites (but not the sizes by themselves) rises at increase of W. The essential influence of PUA on the relative crystallite microstrains in c-phase (consisting of small crystallites ∼10 nm) and slight influence on larger crystallites of m- and t-phases were observed.",
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N2 - The changes of phase composition in polymorphous ZrO2-5wt% Y2O3 (YSZ) nanopowder, size of crystallites and their microstrains induced by influence of powerful ultrasound activation (PUA) were studied by XRD techniques. It was shown that during the process of dry nanopowder sonication the part of tetragonal (t) phase transforms to cubic (c) one, its significant smaller part - to monoclinic (m) phase. With PUA power W increasing from O up to 3 kW the rise of apparent crystallite sizes (ACS) was observed for all the phases. Such increasing the ACS is unusual, as it would be expected decreasing the crystallite sizes because of the destroying action of PU-oscillations on crystalline substances. The analysis of ACS values versus phase composition showed that the smallest in size crystallites of t-phase (with the sizes about 10 nm) transfer to c-phase, therewith the average value of ACS of c-phase increases (but not ACS values themselves) at the expense of rise of crystallite amount with the sizes of ∼10 nm. The larger crystallites of t-phase (sizes about 40 nm) martensitely transfer to m-phase increasing the average value of ACS for this phase. As a result the t-phase loses the most part of its crystallites with small and medium sizes (from 10 up to 40 nm), and the average size of the rest of t-phase crystallites (but not the sizes by themselves) rises at increase of W. The essential influence of PUA on the relative crystallite microstrains in c-phase (consisting of small crystallites ∼10 nm) and slight influence on larger crystallites of m- and t-phases were observed.

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