Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2

E. V. Ilyina, I. V. Mishakov, A. A. Vedyagin, A. F. Bedilo, K. J. Klabunde

Результат исследований: Материалы для книги/типы отчетовМатериалы для конференции

1 цитирование (Scopus)

Выдержка

The developed method for synthesis of binary VOx/MgO aerogels by hydrolysis of the V and Mg alkoxides mixed together followed by gelation and supercritical drying makes it possible to obtain aerogels with exceptionally high surface areas (~ 1200 m2/g) and uniform vanadium distribution. Their dehydration yields nanocrystalline VOx/MgO with nanoparticle size ca. 5 nm. The synthesized nanocrystalline VOx/MgO oxides were used as destructive sorbents for decomposition of halocarbons. The doping of MgO aerogels with a small amount of VOx (1-2%) results in significant acceleration of the reaction with CF 2Cl2 causing deeper MgO transformation to MgF2 and shortening the induction period.

Язык оригиналаАнглийский
Название основной публикацииNanotechnology 2010
Подзаголовок основной публикацииAdvanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
Страницы452-455
Число страниц4
Том1
СостояниеОпубликовано - 2010
Опубликовано для внешнего пользованияДа
СобытиеNanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010 - Anaheim, CA, Соединенные Штаты Америки
Продолжительность: 21 июн 201024 июн 2010

Конференция

КонференцияNanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
СтранаСоединенные Штаты Америки
ГородAnaheim, CA
Период21.6.1024.6.10

Отпечаток

Aerogels
aerogels
Adsorption
adsorption
synthesis
Halocarbons
halocarbons
Vanadium
sorbents
alkoxides
gelation
Gelation
Sorbents
Dehydration
dehydration
Oxides
vanadium
drying
hydrolysis
Hydrolysis

ASJC Scopus subject areas

  • Ceramics and Composites
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Цитировать

Ilyina, E. V., Mishakov, I. V., Vedyagin, A. A., Bedilo, A. F., & Klabunde, K. J. (2010). Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. В Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010 (Том 1, стр. 452-455)

Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. / Ilyina, E. V.; Mishakov, I. V.; Vedyagin, A. A.; Bedilo, A. F.; Klabunde, K. J.

Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Том 1 2010. стр. 452-455.

Результат исследований: Материалы для книги/типы отчетовМатериалы для конференции

Ilyina, EV, Mishakov, IV, Vedyagin, AA, Bedilo, AF & Klabunde, KJ 2010, Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. в Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. том. 1, стр. 452-455, Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010, Anaheim, CA, Соединенные Штаты Америки, 21.6.10.
Ilyina EV, Mishakov IV, Vedyagin AA, Bedilo AF, Klabunde KJ. Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. В Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Том 1. 2010. стр. 452-455
Ilyina, E. V. ; Mishakov, I. V. ; Vedyagin, A. A. ; Bedilo, A. F. ; Klabunde, K. J. / Synthesis of nanocrystalline VOx/MgO aerogels and their application for destructive adsorption of CF2Cl2. Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Том 1 2010. стр. 452-455
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AU - Bedilo, A. F.

AU - Klabunde, K. J.

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