Выдержка
A cobalt(II) iodide complex with bis(3,5-dimethyl-1H-pyrazol-1-yl)methane (L) CoLI 2 has been synthesized, and its single crystals have been obtained. The complex compound was characterized by electron spectroscopy and X-ray diffraction analysis. The compound crystallizes in the monoclinic system (a = 8.4044(4) Å, b = 13.3120(5) Å, c = 14.5824(7) Å; β = 94.7290(10)°; V = 1625.92(13) Å 3; Z = 4; ρ calc = 2.112 g/cm 3; space group P2 1/m). The structure of the complex is molecular mononuclear. L is a cyclic bidentate ligand; the coordination polyhedron of cobalt is a CoN 2I 2 tetrahedron formed by the nitrogen atoms of the pyrazole fragments L and iodine atoms. The complex has π-π stacking interactions between the pyrazole rings of CoLI 2 molecules, binding the molecules into infinite chains along the b axis.
| Язык оригинала | Английский |
|---|---|
| Страницы (с-по) | 1099-1103 |
| Число страниц | 5 |
| Журнал | Journal of Structural Chemistry |
| Том | 46 |
| Номер выпуска | 6 |
| DOI | |
| Состояние | Опубликовано - 1 ноя 2005 |
| Опубликовано для внешнего пользования | Да |
Отпечаток
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
Цитировать
Synthesis and structure of (bis(3,5-dimethyl-1H-pyrazol-1-yl)methane) diiodocobalt(II). / Bushuev, M. B.; Virovets, A. V.; Peresypkina, E. V.; Naumov, D. Yu; Potapov, A. S.; Khlebnikov, A. I.; Vasilevsky, S. F.; Lavrenova, L. G.
В: Journal of Structural Chemistry, Том 46, № 6, 01.11.2005, стр. 1099-1103.Результат исследований: Материалы для журнала › Статья
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TY - JOUR
T1 - Synthesis and structure of (bis(3,5-dimethyl-1H-pyrazol-1-yl)methane) diiodocobalt(II)
AU - Bushuev, M. B.
AU - Virovets, A. V.
AU - Peresypkina, E. V.
AU - Naumov, D. Yu
AU - Potapov, A. S.
AU - Khlebnikov, A. I.
AU - Vasilevsky, S. F.
AU - Lavrenova, L. G.
PY - 2005/11/1
Y1 - 2005/11/1
N2 - A cobalt(II) iodide complex with bis(3,5-dimethyl-1H-pyrazol-1-yl)methane (L) CoLI 2 has been synthesized, and its single crystals have been obtained. The complex compound was characterized by electron spectroscopy and X-ray diffraction analysis. The compound crystallizes in the monoclinic system (a = 8.4044(4) Å, b = 13.3120(5) Å, c = 14.5824(7) Å; β = 94.7290(10)°; V = 1625.92(13) Å 3; Z = 4; ρ calc = 2.112 g/cm 3; space group P2 1/m). The structure of the complex is molecular mononuclear. L is a cyclic bidentate ligand; the coordination polyhedron of cobalt is a CoN 2I 2 tetrahedron formed by the nitrogen atoms of the pyrazole fragments L and iodine atoms. The complex has π-π stacking interactions between the pyrazole rings of CoLI 2 molecules, binding the molecules into infinite chains along the b axis.
AB - A cobalt(II) iodide complex with bis(3,5-dimethyl-1H-pyrazol-1-yl)methane (L) CoLI 2 has been synthesized, and its single crystals have been obtained. The complex compound was characterized by electron spectroscopy and X-ray diffraction analysis. The compound crystallizes in the monoclinic system (a = 8.4044(4) Å, b = 13.3120(5) Å, c = 14.5824(7) Å; β = 94.7290(10)°; V = 1625.92(13) Å 3; Z = 4; ρ calc = 2.112 g/cm 3; space group P2 1/m). The structure of the complex is molecular mononuclear. L is a cyclic bidentate ligand; the coordination polyhedron of cobalt is a CoN 2I 2 tetrahedron formed by the nitrogen atoms of the pyrazole fragments L and iodine atoms. The complex has π-π stacking interactions between the pyrazole rings of CoLI 2 molecules, binding the molecules into infinite chains along the b axis.
KW - Bis(3,5-dimethyl-1H-pyrazol-1-yl)methane
KW - Cobalt(II) iodide
KW - Coordination compound
KW - Crystal structure
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=33748931125&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33748931125&partnerID=8YFLogxK
U2 - 10.1007/s10947-006-0250-7
DO - 10.1007/s10947-006-0250-7
M3 - Article
AN - SCOPUS:33748931125
VL - 46
SP - 1099
EP - 1103
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 6
ER -