Synthesis and reactivity of sulfamoyl azides and 1-sulfamoyl-1,2,3- triazoles

Аннотация

Sulfamoyl azides are readily generated from secondary amines and a novel sulfonyl azide transfer agent, 2,3-dimethyl-1H-imidazolium triflate. They react with alkynes in the presence of a CuTC catalyst forming 1-sulfamoyl-1,2,3- triazoles. The latter are shelf-stable progenitors of rhodium azavinyl carbenes, versatile reactive intermediates that, among other reactions, readily and asymmetrically add to olefins.

Язык оригинала	Английский
Страницы (с-по)	4578-4580
Число страниц	3
Журнал	Organic Letters
Том	13
Номер выпуска	17
DOI	https://doi.org/10.1021/ol201705k
Состояние	Опубликовано - 2 сен 2011
Опубликовано для внешнего пользования	Да

ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Biochemistry

Доступ к документу

10.1021/ol201705k

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Цитировать

Culhane, J. C., & Fokin, V. V. (2011). Synthesis and reactivity of sulfamoyl azides and 1-sulfamoyl-1,2,3- triazoles. Organic Letters, 13(17), 4578-4580. https://doi.org/10.1021/ol201705k

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