Sulfonic acid based cation-exchange resin: A novel proton source for one-pot diazotization-iodination of aromatic amines in water

Victor D. Filimonov, Nadya I. Semenischeva, Elena A. Krasnokutskaya, Alexei N. Tretyakov, Yun Hwang Ho, Ki Whan Chi

Результат исследований: Материалы для журналаСтатья

37 Цитирования (Scopus)

Выдержка

A convenient and simple one-pot method for the preparation of iodoarenes at room temperature has been developed, by sequential diazotization-iodination of aromatic amines with NaNO2/KI in the presence of a sulfonic acid based cation-exchange resin in water. This inexpensive, noncorrosive and eco-friendly synthetic route is general in nature and allows for the preparation of iodoarenes with an electron-donating or -withdrawing group in various positions from the corresponding amines in 50-98% yields.

Язык оригиналаАнглийский
Страницы (с-по)185-187
Число страниц3
ЖурналSynthesis
Номер выпуска2
DOI
СостояниеОпубликовано - 17 янв 2008

Отпечаток

Cation Exchange Resins
Sulfonic Acids
Amines
Protons
Ion exchange
Resins
Positive ions
Acids
Water
Electrons
Temperature

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

Цитировать

Sulfonic acid based cation-exchange resin : A novel proton source for one-pot diazotization-iodination of aromatic amines in water. / Filimonov, Victor D.; Semenischeva, Nadya I.; Krasnokutskaya, Elena A.; Tretyakov, Alexei N.; Ho, Yun Hwang; Chi, Ki Whan.

В: Synthesis, № 2, 17.01.2008, стр. 185-187.

Результат исследований: Материалы для журналаСтатья

@article{0398f391e8f147bb994fcfee5b4270bb,
title = "Sulfonic acid based cation-exchange resin: A novel proton source for one-pot diazotization-iodination of aromatic amines in water",
abstract = "A convenient and simple one-pot method for the preparation of iodoarenes at room temperature has been developed, by sequential diazotization-iodination of aromatic amines with NaNO2/KI in the presence of a sulfonic acid based cation-exchange resin in water. This inexpensive, noncorrosive and eco-friendly synthetic route is general in nature and allows for the preparation of iodoarenes with an electron-donating or -withdrawing group in various positions from the corresponding amines in 50-98{\%} yields.",
keywords = "Aromatic amines, Cation-exchange resin, Diazotization, Iodoarenes, Potassium iodide, Sodium nitrite",
author = "Filimonov, {Victor D.} and Semenischeva, {Nadya I.} and Krasnokutskaya, {Elena A.} and Tretyakov, {Alexei N.} and Ho, {Yun Hwang} and Chi, {Ki Whan}",
year = "2008",
month = "1",
day = "17",
doi = "10.1055/s-2007-990950",
language = "English",
pages = "185--187",
journal = "Synthesis",
issn = "0039-7881",
publisher = "Georg Thieme Verlag",
number = "2",

}

TY - JOUR

T1 - Sulfonic acid based cation-exchange resin

T2 - A novel proton source for one-pot diazotization-iodination of aromatic amines in water

AU - Filimonov, Victor D.

AU - Semenischeva, Nadya I.

AU - Krasnokutskaya, Elena A.

AU - Tretyakov, Alexei N.

AU - Ho, Yun Hwang

AU - Chi, Ki Whan

PY - 2008/1/17

Y1 - 2008/1/17

N2 - A convenient and simple one-pot method for the preparation of iodoarenes at room temperature has been developed, by sequential diazotization-iodination of aromatic amines with NaNO2/KI in the presence of a sulfonic acid based cation-exchange resin in water. This inexpensive, noncorrosive and eco-friendly synthetic route is general in nature and allows for the preparation of iodoarenes with an electron-donating or -withdrawing group in various positions from the corresponding amines in 50-98% yields.

AB - A convenient and simple one-pot method for the preparation of iodoarenes at room temperature has been developed, by sequential diazotization-iodination of aromatic amines with NaNO2/KI in the presence of a sulfonic acid based cation-exchange resin in water. This inexpensive, noncorrosive and eco-friendly synthetic route is general in nature and allows for the preparation of iodoarenes with an electron-donating or -withdrawing group in various positions from the corresponding amines in 50-98% yields.

KW - Aromatic amines

KW - Cation-exchange resin

KW - Diazotization

KW - Iodoarenes

KW - Potassium iodide

KW - Sodium nitrite

UR - http://www.scopus.com/inward/record.url?scp=38849118349&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=38849118349&partnerID=8YFLogxK

U2 - 10.1055/s-2007-990950

DO - 10.1055/s-2007-990950

M3 - Article

AN - SCOPUS:38849118349

SP - 185

EP - 187

JO - Synthesis

JF - Synthesis

SN - 0039-7881

IS - 2

ER -