Structure of the paramagnetic products of thiocyanate photolysis at 77 K

L. P. Eremin, O. Kh Poleshchuk, V. A. Poluboyarov, L. V. Babovskaya, A. E. Lapin

Результат исследований: Материалы для журнала › Статья › рецензирование

Аннотация

Solid paramagnetic products of thiocyanate photolysis were studied at 77 K by EPR and diffuse reflectance spectroscopy. Ab initio calculations of the electronic structure of these products have been carried out. Direct UV irradiation can generate the SCN ⁰ radical due to ionization of the thiocyanate ion. Interaction of the SCN ⁰ radical with the neighboring thiocyanate ion forms another radical product of photolysis - (SCN) ₂ ^- radical ion.

Язык оригинала	Английский
Страницы (с-по)	404-409
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	44
Номер выпуска	3
DOI	https://doi.org/10.1023/B:JORY.0000009667.51492.c8
Состояние	Опубликовано - мая 2003

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

Доступ к документу

10.1023/B:JORY.0000009667.51492.c8

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Structure of the paramagnetic products of thiocyanate photolysis at 77 K. / Eremin, L. P.; Poleshchuk, O. Kh; Poluboyarov, V. A.; Babovskaya, L. V.; Lapin, A. E.

В: Journal of Structural Chemistry, Том 44, № 3, 05.2003, стр. 404-409.

Результат исследований: Материалы для журнала › Статья › рецензирование

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AU - Lapin, A. E.

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