Saccharin-based μ-oxo imidoiodane: A readily available and highly reactive reagent for electrophilic amination

Akira Yoshimura, Steven R. Koski, Jonathan M. Fuchs, Akio Saito, Victor N. Nemykin, Viktor V. Zhdankin

Результат исследований: Материалы для журналаСтатья

21 Цитирования (Scopus)

Аннотация

Three new saccharin-based hypervalent iodine compounds were prepared by the reaction of saccharine with (diacetoxyiodo)arenes or acetoxybenziodoxole. Structures of these new imidoiodanes were established by X-ray crystallography. The saccharin-based μ-oxo-bridged imidoiodane readily reacts with silyl enol ethers under mild conditions to give the corresponding α-aminated carbonyl compounds in moderate yields. Sweet saccharin: Three new saccharin-derived hypervalent iodine compounds were prepared by the reaction of saccharine with (diacetoxyiodo)arenes or acetoxybenziodoxole. The saccharin-based μ-oxo-bridged imidoiodane readily reacts with silyl enol ethers to give the corresponding α-aminated carbonyl compounds in moderate yields.

Язык оригиналаАнглийский
Страницы (с-по)5328-5331
Число страниц4
ЖурналChemistry - A European Journal
Том21
Номер выпуска14
DOI
СостояниеОпубликовано - 27 мар 2015
Опубликовано для внешнего пользованияДа

ASJC Scopus subject areas

  • Chemistry(all)

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