Аннотация
Three new saccharin-based hypervalent iodine compounds were prepared by the reaction of saccharine with (diacetoxyiodo)arenes or acetoxybenziodoxole. Structures of these new imidoiodanes were established by X-ray crystallography. The saccharin-based μ-oxo-bridged imidoiodane readily reacts with silyl enol ethers under mild conditions to give the corresponding α-aminated carbonyl compounds in moderate yields. Sweet saccharin: Three new saccharin-derived hypervalent iodine compounds were prepared by the reaction of saccharine with (diacetoxyiodo)arenes or acetoxybenziodoxole. The saccharin-based μ-oxo-bridged imidoiodane readily reacts with silyl enol ethers to give the corresponding α-aminated carbonyl compounds in moderate yields.
Язык оригинала | Английский |
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Страницы (с-по) | 5328-5331 |
Число страниц | 4 |
Журнал | Chemistry - A European Journal |
Том | 21 |
Номер выпуска | 14 |
DOI | |
Состояние | Опубликовано - 27 мар 2015 |
Опубликовано для внешнего пользования | Да |
ASJC Scopus subject areas
- Chemistry(all)