Аннотация
Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.
| Язык оригинала | Английский |
|---|---|
| Страницы (с-по) | 49-57 |
| Число страниц | 9 |
| Журнал | Polymer Science - Series C |
| Том | 61 |
| Номер выпуска | 1 |
| DOI | |
| Состояние | Опубликовано - 1 сен 2019 |
ASJC Scopus subject areas
- Chemistry(all)
- Polymers and Plastics
- Materials Chemistry
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Цитировать
Lyapkov, A. A., Bozhenkova, G. S., Smirnova, N. A., Prokudina, N. I., Yusubov, M. S., & Verpoort, F. (2019). Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer. Polymer Science - Series C, 61(1), 49-57. https://doi.org/10.1134/S1811238219010119