Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer

A. A. Lyapkov, G. S. Bozhenkova, N. A. Smirnova, N. I. Prokudina, M. S. Yusubov, F. Verpoort

Исследовательская школа химических и биомедицинских технологий

Результат исследований: Материалы для журнала › Статья › рецензирование

Аннотация

Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

Язык оригинала	Английский
Страницы (с-по)	49-57
Число страниц	9
Журнал	Polymer Science - Series C
Том	61
Номер выпуска	1
DOI	https://doi.org/10.1134/S1811238219010119
Состояние	Опубликовано - 1 сен 2019

ASJC Scopus subject areas

Chemistry(all)
Polymers and Plastics
Materials Chemistry

Доступ к документу

10.1134/S1811238219010119

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Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer. / Lyapkov, A. A.; Bozhenkova, G. S.; Smirnova, N. A.; Prokudina, N. I.; Yusubov, M. S.; Verpoort, F.

В: Polymer Science - Series C, Том 61, № 1, 01.09.2019, стр. 49-57.

Результат исследований: Материалы для журнала › Статья › рецензирование

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abstract = "Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.",

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AU - Lyapkov, A. A.

AU - Bozhenkova, G. S.

AU - Smirnova, N. A.

AU - Prokudina, N. I.

AU - Yusubov, M. S.

AU - Verpoort, F.

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AB - Abstract: In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.

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