Preparation and X-ray structural study of 1-arylbenziodoxolones

Результат исследований: Материалы для журналаСтатья

23 Цитирования (Scopus)


Various 1-arylbenziodoxolones can be conveniently prepared from 2-iodobenzoic acid and arenes by a one-pot procedure using Oxone (2KHSO 5·KHSO4·K2SO4) as an inexpensive and environmentally safe oxidant. This procedure is also applicable for the synthesis of the 7-methylbenziodoxolone ring system using 2-iodo-3-methylbenzoic acid as starting compound. Structures of four 1-arylbenziodoxolone derivatives were established by single-crystal X-ray diffraction analysis. An enhanced reactivity of 1-aryl-7-methylbenziodoxolones toward nucleophiles compared to unsubstituted 1-arylbenziodoxolones has been found.

Язык оригиналаАнглийский
Страницы (с-по)3767-3773
Число страниц7
ЖурналJournal of Organic Chemistry
Номер выпуска8
СостояниеОпубликовано - 19 апр 2013

ASJC Scopus subject areas

  • Organic Chemistry

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