Preparation and structure of phenolic aryliodonium salts

Akira Yoshimura, Michael T. Shea, Olga Guselnikova, Pavel S. Postnikov, Gregory T. Rohde, Akio Saito, Mekhman S. Yusubov, Victor N. Nemykin, Viktor V. Zhdankin

Исследовательская школа химических и биомедицинских технологий

Результат исследований: Материалы для журнала › Статья › рецензирование

5 Цитирования (Scopus)

Аннотация

Phenol based aryliodonium salts were prepared by the reaction of [hydroxy(tosyloxy)iodo]arenes with aryl silyl ethers in the presence of trifluoromethanesulfonic acid. Structures of several aryliodonium salts with the hydroxy group in the para-position of the phenyl ring were established by single crystal X-ray crystallography. Under basic conditions, 4-hydroxyphenyl(phenyl)iodonium salts form a dimeric hypervalent iodine(iii) complex, oxyphenyl(phenyl)iodonium ylidic salt, the solid structure of which was confirmed by X-ray crystallography. Phenolic iodonium salts are potentially useful phenol transfer reagents in reactions with various anionic nucleophiles.

Язык оригинала	Английский
Страницы (с-по)	10363-10366
Число страниц	4
Журнал	Chemical Communications
Том	54
Номер выпуска	73
DOI	https://doi.org/10.1039/C8CC06211K
Состояние	Опубликовано - 1 янв 2018

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Доступ к документу

10.1039/C8CC06211K

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Цитировать

Preparation and structure of phenolic aryliodonium salts. / Yoshimura, Akira; Shea, Michael T.; Guselnikova, Olga ; Postnikov, Pavel S.; Rohde, Gregory T.; Saito, Akio; Yusubov, Mekhman S.; Nemykin, Victor N.; Zhdankin, Viktor V.

В: Chemical Communications, Том 54, № 73, 01.01.2018, стр. 10363-10366.

Результат исследований: Материалы для журнала › Статья › рецензирование

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AU - Shea, Michael T.

AU - Guselnikova, Olga

AU - Postnikov, Pavel S.

AU - Rohde, Gregory T.

AU - Saito, Akio

AU - Yusubov, Mekhman S.

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor V.

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