"On water": Unique reactivity of organic compounds in aqueous suspension

Sridhar Narayan, John Muldoon, M. G. Finn, Valery V. Fokin, Hartmuth C. Kolb, K. Barry Sharpless

Результат исследований: Материалы для журналаСтатья

1222 Цитирования (Scopus)

Аннотация

(Chemical Equation Presented) Water, the medium of choice: Many reactions, such as Claisen rearrangements (see scheme), are dramatically accelerated when performed in aqueous suspension ("on water") relative to organic (Table Presented) solvents or even neat conditions. Low miscibility of organic compounds with water is not detrimental: in fact, it facilitates the isolation of products.

Язык оригиналаАнглийский
Страницы (с-по)3275-3279
Число страниц5
ЖурналAngewandte Chemie - International Edition
Том44
Номер выпуска21
DOI
СостояниеОпубликовано - 20 мая 2005
Опубликовано для внешнего пользованияДа

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ASJC Scopus subject areas

  • Chemistry(all)

Цитировать

Narayan, S., Muldoon, J., Finn, M. G., Fokin, V. V., Kolb, H. C., & Sharpless, K. B. (2005). "On water": Unique reactivity of organic compounds in aqueous suspension. Angewandte Chemie - International Edition, 44(21), 3275-3279. https://doi.org/10.1002/anie.200462883