On the local mode behaviour of the XH2/XD2 and XD/XH fragments with respect to the deuterated species of the near local mode XH 3 (C3v ) molecule

Результат исследований: Материалы для журналаСтатья

8 Цитирования (Scopus)

Аннотация

Effect of isotopic substitution in the near local mode, XH3 (C3v), molecules is considered. On that basis it is shown that the spectroscopic properties of deuterated and/or di-deuterated isotopic species of the XH3 (C3v) molecule with the value of interbond angle close to /2 are analogous to the spectroscopic properties of its separate fragments: of a three-atomic local mode 'molecule' XH2/XD2 and of a diatomic XD/XH 'molecule'. The phosphine molecule is considered as an illustration.

Язык оригиналаАнглийский
Страницы (с-по)1409-1416
Число страниц8
ЖурналMolecular Physics
Том107
Номер выпуска14
DOI
СостояниеОпубликовано - 1 янв 2009

ASJC Scopus subject areas

  • Biophysics
  • Molecular Biology
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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