N2-Cu-F: A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy

Simon G. Francis, Steven L. Matthews, Oleg Kh Poleshchuk, Nicholas R. Walker, Anthony C. Legon

    Результат исследований: Материалы для журналаСтатья

    31 Цитирования (Scopus)

    Выдержка

    (Graph Presented) Dinitrogen bound: A compound formed by dinitrogen with cuprous fluoride has been synthesized by laser ablation of a copper rod in the presence of a source of F atoms and N2. The rotational spectrum of 15N2-Cu-F has been assigned, and the rotational, centrifugal, and nuclear hyperfine coupling constants have been determined. These constants and electronic structure calculations give conclusions about the nature of this novel molecule.

    Язык оригиналаАнглийский
    Страницы (с-по)6341-6343
    Число страниц3
    ЖурналAngewandte Chemie - International Edition
    Том45
    Номер выпуска38
    DOI
    СостояниеОпубликовано - 25 сен 2006

    Отпечаток

    Laser ablation
    Fluorides
    Electronic structure
    Copper
    Spectroscopy
    Atoms
    Molecules

    ASJC Scopus subject areas

    • Chemistry(all)

    Цитировать

    N2-Cu-F : A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy. / Francis, Simon G.; Matthews, Steven L.; Poleshchuk, Oleg Kh; Walker, Nicholas R.; Legon, Anthony C.

    В: Angewandte Chemie - International Edition, Том 45, № 38, 25.09.2006, стр. 6341-6343.

    Результат исследований: Материалы для журналаСтатья

    Francis, SG, Matthews, SL, Poleshchuk, OK, Walker, NR & Legon, AC 2006, 'N2-Cu-F: A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy', Angewandte Chemie - International Edition, том. 45, № 38, стр. 6341-6343. https://doi.org/10.1002/anie.200601988
    Francis, Simon G. ; Matthews, Steven L. ; Poleshchuk, Oleg Kh ; Walker, Nicholas R. ; Legon, Anthony C. / N2-Cu-F : A complex of dinitrogen and cuprous fluoride characterized by rotational spectroscopy. В: Angewandte Chemie - International Edition. 2006 ; Том 45, № 38. стр. 6341-6343.
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    AU - Poleshchuk, Oleg Kh

    AU - Walker, Nicholas R.

    AU - Legon, Anthony C.

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    AB - (Graph Presented) Dinitrogen bound: A compound formed by dinitrogen with cuprous fluoride has been synthesized by laser ablation of a copper rod in the presence of a source of F atoms and N2. The rotational spectrum of 15N2-Cu-F has been assigned, and the rotational, centrifugal, and nuclear hyperfine coupling constants have been determined. These constants and electronic structure calculations give conclusions about the nature of this novel molecule.

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    KW - Electronic structure

    KW - Fluorine

    KW - Rotational spectroscopy

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