Ni-Cu and Ni-Co alloys: Synthesis, structure, and catalytic activity for the decomposition of chlorinated hydrocarbons

A. V. Rudnev, A. S. Lysakova, Pavel E. Plyusnin, Yu I. Bauman, Yu V. Shubin, I. V. Mishakov, Aleksey A. Vedyagin, R. A. Buyanov

Результат исследований: Материалы для журналаСтатья

13 Цитирования (Scopus)

Выдержка

Homogeneous Ni x Cu1 - x and Ni x Co 1 - x (x = 0.90-0.99) alloys have been prepared through the coprecipitation of precursors (hydroxides or carbonates) and reduction of the precipitate. The formation of single-phase Ni x M1 - x alloys in all of the samples has been confirmed by X-ray diffraction. We have assessed the catalytic activity of the alloys for 1,2-dichloroethane decomposition with carbon nanomaterial (CNM) formation. The highest catalytic activity (CNM yield, 26-27 g/gcat) was offered by the nickel alloys containing ∼1 at % Cu or Co. The carbon material obtained has the form of segmented submicron wires with high morphological uniformity.

Язык оригиналаАнглийский
Страницы (с-по)566-571
Число страниц6
ЖурналInorganic Materials
Том50
Номер выпуска6
DOI
СостояниеОпубликовано - 2014
Опубликовано для внешнего пользованияДа

Отпечаток

Chlorinated Hydrocarbons
Catalyst activity
Carbon
Decomposition
Nanostructured materials
Hydroxides
Carbonates
Nickel alloys
Coprecipitation
Precipitates
Wire
X ray diffraction

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Chemical Engineering(all)
  • Materials Chemistry
  • Metals and Alloys

Цитировать

Ni-Cu and Ni-Co alloys : Synthesis, structure, and catalytic activity for the decomposition of chlorinated hydrocarbons. / Rudnev, A. V.; Lysakova, A. S.; Plyusnin, Pavel E.; Bauman, Yu I.; Shubin, Yu V.; Mishakov, I. V.; Vedyagin, Aleksey A.; Buyanov, R. A.

В: Inorganic Materials, Том 50, № 6, 2014, стр. 566-571.

Результат исследований: Материалы для журналаСтатья

Rudnev, A. V. ; Lysakova, A. S. ; Plyusnin, Pavel E. ; Bauman, Yu I. ; Shubin, Yu V. ; Mishakov, I. V. ; Vedyagin, Aleksey A. ; Buyanov, R. A. / Ni-Cu and Ni-Co alloys : Synthesis, structure, and catalytic activity for the decomposition of chlorinated hydrocarbons. В: Inorganic Materials. 2014 ; Том 50, № 6. стр. 566-571.
@article{21798db8963541d1a7ce73498459f7ac,
title = "Ni-Cu and Ni-Co alloys: Synthesis, structure, and catalytic activity for the decomposition of chlorinated hydrocarbons",
abstract = "Homogeneous Ni x Cu1 - x and Ni x Co 1 - x (x = 0.90-0.99) alloys have been prepared through the coprecipitation of precursors (hydroxides or carbonates) and reduction of the precipitate. The formation of single-phase Ni x M1 - x alloys in all of the samples has been confirmed by X-ray diffraction. We have assessed the catalytic activity of the alloys for 1,2-dichloroethane decomposition with carbon nanomaterial (CNM) formation. The highest catalytic activity (CNM yield, 26-27 g/gcat) was offered by the nickel alloys containing ∼1 at {\%} Cu or Co. The carbon material obtained has the form of segmented submicron wires with high morphological uniformity.",
author = "Rudnev, {A. V.} and Lysakova, {A. S.} and Plyusnin, {Pavel E.} and Bauman, {Yu I.} and Shubin, {Yu V.} and Mishakov, {I. V.} and Vedyagin, {Aleksey A.} and Buyanov, {R. A.}",
year = "2014",
doi = "10.1134/S0020168514060156",
language = "English",
volume = "50",
pages = "566--571",
journal = "Inorganic Materials",
issn = "0020-1685",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "6",

}

TY - JOUR

T1 - Ni-Cu and Ni-Co alloys

T2 - Synthesis, structure, and catalytic activity for the decomposition of chlorinated hydrocarbons

AU - Rudnev, A. V.

AU - Lysakova, A. S.

AU - Plyusnin, Pavel E.

AU - Bauman, Yu I.

AU - Shubin, Yu V.

AU - Mishakov, I. V.

AU - Vedyagin, Aleksey A.

AU - Buyanov, R. A.

PY - 2014

Y1 - 2014

N2 - Homogeneous Ni x Cu1 - x and Ni x Co 1 - x (x = 0.90-0.99) alloys have been prepared through the coprecipitation of precursors (hydroxides or carbonates) and reduction of the precipitate. The formation of single-phase Ni x M1 - x alloys in all of the samples has been confirmed by X-ray diffraction. We have assessed the catalytic activity of the alloys for 1,2-dichloroethane decomposition with carbon nanomaterial (CNM) formation. The highest catalytic activity (CNM yield, 26-27 g/gcat) was offered by the nickel alloys containing ∼1 at % Cu or Co. The carbon material obtained has the form of segmented submicron wires with high morphological uniformity.

AB - Homogeneous Ni x Cu1 - x and Ni x Co 1 - x (x = 0.90-0.99) alloys have been prepared through the coprecipitation of precursors (hydroxides or carbonates) and reduction of the precipitate. The formation of single-phase Ni x M1 - x alloys in all of the samples has been confirmed by X-ray diffraction. We have assessed the catalytic activity of the alloys for 1,2-dichloroethane decomposition with carbon nanomaterial (CNM) formation. The highest catalytic activity (CNM yield, 26-27 g/gcat) was offered by the nickel alloys containing ∼1 at % Cu or Co. The carbon material obtained has the form of segmented submicron wires with high morphological uniformity.

UR - http://www.scopus.com/inward/record.url?scp=84902511406&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84902511406&partnerID=8YFLogxK

U2 - 10.1134/S0020168514060156

DO - 10.1134/S0020168514060156

M3 - Article

AN - SCOPUS:84902511406

VL - 50

SP - 566

EP - 571

JO - Inorganic Materials

JF - Inorganic Materials

SN - 0020-1685

IS - 6

ER -