Аннотация
On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.
Язык оригинала | Английский |
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Страницы (с-по) | 1106-1109 |
Число страниц | 4 |
Журнал | Soviet Physics Journal |
Том | 18 |
Номер выпуска | 8 |
DOI | |
Состояние | Опубликовано - 1 авг 1975 |
Опубликовано для внешнего пользования | Да |
ASJC Scopus subject areas
- Physics and Astronomy(all)