Method of the effective flexible gyroscope in polyatomic molecules

Аннотация

On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.

Язык оригинала	Английский
Страницы (с-по)	1106-1109
Число страниц	4
Журнал	Soviet Physics Journal
Том	18
Номер выпуска	8
DOI	https://doi.org/10.1007/BF01110030
Состояние	Опубликовано - 1 авг 1975
Опубликовано для внешнего пользования	Да

ASJC Scopus subject areas

Physics and Astronomy(all)

Доступ к документу

10.1007/BF01110030

Fingerprint Подробные сведения о темах исследования «Method of the effective flexible gyroscope in polyatomic molecules». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

@article{d514fb684e164cffbb9ab4182bf05ccd,

title = "Method of the effective flexible gyroscope in polyatomic molecules",

abstract = "On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the {"}effective{"} rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.",

author = "Makushkin, {Yu S.} and Ulenikov, {O. N.}",

year = "1975",

month = aug,

day = "1",

doi = "10.1007/BF01110030",

language = "English",

volume = "18",

pages = "1106--1109",

journal = "Russian Physics Journal",

issn = "1064-8887",

publisher = "Consultants Bureau",

number = "8",

}

TY - JOUR

T1 - Method of the effective flexible gyroscope in polyatomic molecules

AU - Makushkin, Yu S.

AU - Ulenikov, O. N.

PY - 1975/8/1

Y1 - 1975/8/1

N2 - On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.

AB - On the basis of the general equations of perturbation theory a procedure is suggested for the partial diagonalization of the vibrational-rotational Hamiltonian of a molecule with respect to the vibrational quantum numbers of a nondegenerate vibrational state. Equations are derived for the complete vibrational-rotational wave function and the "effective" rotational Hamiltonian, which is constructed in such a way that the total energy is represented in the form of a sum of the vibrational and rotational energies.

UR - http://www.scopus.com/inward/record.url?scp=34250390499&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250390499&partnerID=8YFLogxK

U2 - 10.1007/BF01110030

DO - 10.1007/BF01110030

M3 - Article

AN - SCOPUS:34250390499

VL - 18

SP - 1106

EP - 1109

JO - Russian Physics Journal

JF - Russian Physics Journal

SN - 1064-8887

IS - 8

ER -