Mechanism of reaction between Cobalt(II) oxide and ammonium chloride

V. A. Borisov, A. N. D'yachenko, R. I. Kraidenko

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Аннотация

A reaction between cobalt oxide and ammonium chloride was studied. A possible mechanism of this reaction was determined by TGA and DSC. The reaction products were identified by IR spectroscopy, chemical and XRD analyses. A multistage mechanism was established for reaction between cobalt oxide and ammonium chloride. Cobalt chloride was determined to be the final product; the reaction occurs via the for-mation and decomposition of (NH ₄) ₃CoCl ₅, (NH ₄) ₂CoCl ₄, and NH ₄CoCl ₃.

Язык оригинала	Английский
Страницы (с... по...)	923-926
Количество страниц	4
Журнал	Russian Journal of Inorganic Chemistry
Том	57
Номер выпуска	7
DOI	https://doi.org/10.1134/S0036023612070066
Статус публикации	Опубликовано - июл 2012

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ASJC Scopus subject areas

Inorganic Chemistry

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Borisov, V. A., D'yachenko, A. N., & Kraidenko, R. I. (2012). Mechanism of reaction between Cobalt(II) oxide and ammonium chloride. Russian Journal of Inorganic Chemistry, 57(7), 923-926. https://doi.org/10.1134/S0036023612070066

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AB - A reaction between cobalt oxide and ammonium chloride was studied. A possible mechanism of this reaction was determined by TGA and DSC. The reaction products were identified by IR spectroscopy, chemical and XRD analyses. A multistage mechanism was established for reaction between cobalt oxide and ammonium chloride. Cobalt chloride was determined to be the final product; the reaction occurs via the for-mation and decomposition of (NH 4) 3CoCl 5, (NH 4) 2CoCl 4, and NH 4CoCl 3.

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Доступ к документу

10.1134/S0036023612070066