Lead(II) Complexes with the B12H11NEt3 - and 1-B10H9SMe2 - closo Anions

Аннотация

Lead(II) complexes [Pb(Bipy)₂][B₁₂H₁₁NEt₃]₂, [Pb(py₂NH)₂][B₁₂H₁₁NEt ₃]₂, [Pb(Bipy)₂][1-B₁₀H₉SMe₂] ₂, and [Pb(Py₂NH)₂][1-B₁₀H₉SMe ₂]₂ are prepared. The complexes are characterized by elemental analysis and IR spectroscopy. The structure of the complexes is considered in comparison with the available data on the structure of the complexes with nonsubstituted closo anions. Conclusions on the change of the donor ability of monosubstituted hydroborate anions are made.

Язык оригинала	Английский
Страницы (с-по)	499-502
Число страниц	4
Журнал	Russian Journal of Inorganic Chemistry
Том	43
Номер выпуска	4
Состояние	Опубликовано - апр 1998
Опубликовано для внешнего пользования	Да

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

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Lead(II) Complexes with the B₁₂H₁₁NEt₃ ^- and 1-B₁₀H₉SMe₂ ^- closo Anions. / Orlova, A. M.; Goeva, L. V.; Solntsev, K. A.; Kuznetsov, N. T.

В: Russian Journal of Inorganic Chemistry, Том 43, № 4, 04.1998, стр. 499-502.

Результат исследований: Материалы для журнала › Статья › рецензирование

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title = "Lead(II) Complexes with the B12H11NEt3 - and 1-B10H9SMe2 - closo Anions",

abstract = "Lead(II) complexes [Pb(Bipy)2][B12H11NEt3]2, [Pb(py2NH)2][B12H11NEt 3]2, [Pb(Bipy)2][1-B10H9SMe2] 2, and [Pb(Py2NH)2][1-B10H9SMe 2]2 are prepared. The complexes are characterized by elemental analysis and IR spectroscopy. The structure of the complexes is considered in comparison with the available data on the structure of the complexes with nonsubstituted closo anions. Conclusions on the change of the donor ability of monosubstituted hydroborate anions are made.",

author = "Orlova, {A. M.} and Goeva, {L. V.} and Solntsev, {K. A.} and Kuznetsov, {N. T.}",

year = "1998",

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T1 - Lead(II) Complexes with the B12H11NEt3 - and 1-B10H9SMe2 - closo Anions

AU - Orlova, A. M.

AU - Goeva, L. V.

AU - Solntsev, K. A.

AU - Kuznetsov, N. T.

PY - 1998/4

Y1 - 1998/4

N2 - Lead(II) complexes [Pb(Bipy)2][B12H11NEt3]2, [Pb(py2NH)2][B12H11NEt 3]2, [Pb(Bipy)2][1-B10H9SMe2] 2, and [Pb(Py2NH)2][1-B10H9SMe 2]2 are prepared. The complexes are characterized by elemental analysis and IR spectroscopy. The structure of the complexes is considered in comparison with the available data on the structure of the complexes with nonsubstituted closo anions. Conclusions on the change of the donor ability of monosubstituted hydroborate anions are made.

AB - Lead(II) complexes [Pb(Bipy)2][B12H11NEt3]2, [Pb(py2NH)2][B12H11NEt 3]2, [Pb(Bipy)2][1-B10H9SMe2] 2, and [Pb(Py2NH)2][1-B10H9SMe 2]2 are prepared. The complexes are characterized by elemental analysis and IR spectroscopy. The structure of the complexes is considered in comparison with the available data on the structure of the complexes with nonsubstituted closo anions. Conclusions on the change of the donor ability of monosubstituted hydroborate anions are made.

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