Lanthanide paramagnetic probes for NMR spectroscopic studies of molecular conformational dynamics in solution: Applications to macrocyclic molecules

S. P. Babailov

Результат исследований: Материалы для журналаОбзорная статья

56 Цитирования (Scopus)

Выдержка

A study was conducted to demonstrate the application of lanthanide paramagnetic probes for nuclear magnetic resonance spectroscopic studies of molecular conformational dynamics in solution to macrocyclic molecules. It was found that lanthanide complexes in solution exhibited a well-defined luminescence, which was characterized by narrow emission bands, large Stokes' shifts, and long excited-state lifetimes. A number of NMR investigations of intramolecular dynamics for lanthanide complexes in aqueous solutions, with other macrocyclic ligands were also considered for comparison. The methodology of paramagnetic Ce, Nd, Pr, Eu, Dy, and Yb probe applications for studying the enthalpy and entropy changes in chemical exchange processes was also investigated. The advantages of the methodology in comparison with DNMR studies of diamagnetic substances were also demonstrated.

Язык оригиналаАнглийский
Страницы (с-по)1-21
Число страниц21
ЖурналProgress in Nuclear Magnetic Resonance Spectroscopy
Том52
Номер выпуска1
DOI
СостояниеОпубликовано - 30 янв 2008
Опубликовано для внешнего пользованияДа

Отпечаток

Lanthanoid Series Elements
Molecular Dynamics Simulation
Molecular dynamics
Nuclear magnetic resonance
methodology
molecular dynamics
nuclear magnetic resonance
Molecules
probes
Chemical Phenomena
molecules
enthalpy
Entropy
entropy
luminescence
Luminescence
aqueous solutions
Excited states
life (durability)
ligands

ASJC Scopus subject areas

  • Spectroscopy
  • Radiology Nuclear Medicine and imaging
  • Condensed Matter Physics

Цитировать

Lanthanide paramagnetic probes for NMR spectroscopic studies of molecular conformational dynamics in solution : Applications to macrocyclic molecules. / Babailov, S. P.

В: Progress in Nuclear Magnetic Resonance Spectroscopy, Том 52, № 1, 30.01.2008, стр. 1-21.

Результат исследований: Материалы для журналаОбзорная статья

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N2 - A study was conducted to demonstrate the application of lanthanide paramagnetic probes for nuclear magnetic resonance spectroscopic studies of molecular conformational dynamics in solution to macrocyclic molecules. It was found that lanthanide complexes in solution exhibited a well-defined luminescence, which was characterized by narrow emission bands, large Stokes' shifts, and long excited-state lifetimes. A number of NMR investigations of intramolecular dynamics for lanthanide complexes in aqueous solutions, with other macrocyclic ligands were also considered for comparison. The methodology of paramagnetic Ce, Nd, Pr, Eu, Dy, and Yb probe applications for studying the enthalpy and entropy changes in chemical exchange processes was also investigated. The advantages of the methodology in comparison with DNMR studies of diamagnetic substances were also demonstrated.

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KW - DOTA-like ligands

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