Investigation of the Fine Energy Structure of the (0100, E) and (0001, F 2) Vibrational States of the 73GeH4 Molecule

Результат исследований: Материалы для журналаСтатья

Выдержка

The IR spectrum of the 73GeH4 molecule is recorded with a Bruker IFS 125HR high-resolution Fourier spectrometer in the range 650–1100 cm–1 and then analyzed; 1127 transitions with Jmax = 19 are assigned to the ν4 and ν2 bands of the 73GeH4 molecule. The rotational and centrifugal parameters of tetrahedral splitting and the Coriolis interaction parameters for the (0100, E) ground and (0001, F2) vibrational states are determined by varying positions of the experimental lines. The obtained set of the spectroscopic parameters reproduces the initial experimental data with the accuracy close to the experimental one.

Язык оригиналаАнглийский
Страницы (с-по)1281-1287
Число страниц7
ЖурналRussian Physics Journal
Том61
Номер выпуска7
DOI
СостояниеОпубликовано - 1 ноя 2018

Отпечаток

vibrational states
molecules
energy
spectrometers
high resolution
interactions

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Цитировать

Investigation of the Fine Energy Structure of the (0100, E) and (0001, F 2) Vibrational States of the 73GeH4 Molecule. / Raspopova, N. I.; Sklyarova, E. A.; Sennikov, P. G.

В: Russian Physics Journal, Том 61, № 7, 01.11.2018, стр. 1281-1287.

Результат исследований: Материалы для журналаСтатья

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T1 - Investigation of the Fine Energy Structure of the (0100, E) and (0001, F 2) Vibrational States of the 73GeH4 Molecule

AU - Raspopova, N. I.

AU - Sklyarova, E. A.

AU - Sennikov, P. G.

PY - 2018/11/1

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N2 - The IR spectrum of the 73GeH4 molecule is recorded with a Bruker IFS 125HR high-resolution Fourier spectrometer in the range 650–1100 cm–1 and then analyzed; 1127 transitions with Jmax = 19 are assigned to the ν4 and ν2 bands of the 73GeH4 molecule. The rotational and centrifugal parameters of tetrahedral splitting and the Coriolis interaction parameters for the (0100, E) ground and (0001, F2) vibrational states are determined by varying positions of the experimental lines. The obtained set of the spectroscopic parameters reproduces the initial experimental data with the accuracy close to the experimental one.

AB - The IR spectrum of the 73GeH4 molecule is recorded with a Bruker IFS 125HR high-resolution Fourier spectrometer in the range 650–1100 cm–1 and then analyzed; 1127 transitions with Jmax = 19 are assigned to the ν4 and ν2 bands of the 73GeH4 molecule. The rotational and centrifugal parameters of tetrahedral splitting and the Coriolis interaction parameters for the (0100, E) ground and (0001, F2) vibrational states are determined by varying positions of the experimental lines. The obtained set of the spectroscopic parameters reproduces the initial experimental data with the accuracy close to the experimental one.

KW - IR spectroscopy

KW - rovibrational spectrum

KW - spectroscopic parameters

KW - spherical top molecules

KW - tetrahedral splittings

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