Interaction of bulk nickel and nichrome with halogenated butanes

Roman M. Kenzhin, Yuri I. Bauman, Alexander M. Volodin, Ilya V. Mishakov, Aleksey A. Vedyagin

Результат исследований: Материалы для журналаСтатья

Выдержка

Catalytic chemical vapor deposition of halogenated butanes over bulk nickel-containing samples was studied. Butyl iodide and butyl bromide were used as substrates containing both hydrogen and halogen molecules. The experiments were performed in a flow reactor system as well as reaction under autogenic pressure at elevated temperature conditions. Scanning and transmission electron microscopies and ferromagnetic resonance spectroscopy were applied to examine the samples. The formation of structured particles of micron size was observed when nickel ribbon or nichrome wire was used as a bulk sample. The intermediates were shown to be stable in a narrow temperature range. The morphology of the resulting microcrystals was different depending on the metal precursor.

Язык оригиналаАнглийский
Страницы (с-по)1-10
Число страниц10
ЖурналReaction Kinetics, Mechanisms and Catalysis
Том122
Номер выпуска2
DOI
СостояниеПринято/в печати - 26 сен 2017

Отпечаток

Butanes
Nichrome (trademark)
Butane
butanes
Nickel
nickel
Ferromagnetic resonance
Microcrystals
Halogens
Iodides
Hydrogen
Chemical vapor deposition
Metals
microcrystals
interactions
Spectroscopy
Wire
ferromagnetic resonance
Transmission electron microscopy
halogens

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Цитировать

Interaction of bulk nickel and nichrome with halogenated butanes. / Kenzhin, Roman M.; Bauman, Yuri I.; Volodin, Alexander M.; Mishakov, Ilya V.; Vedyagin, Aleksey A.

В: Reaction Kinetics, Mechanisms and Catalysis, Том 122, № 2, 26.09.2017, стр. 1-10.

Результат исследований: Материалы для журналаСтатья

Kenzhin, Roman M. ; Bauman, Yuri I. ; Volodin, Alexander M. ; Mishakov, Ilya V. ; Vedyagin, Aleksey A. / Interaction of bulk nickel and nichrome with halogenated butanes. В: Reaction Kinetics, Mechanisms and Catalysis. 2017 ; Том 122, № 2. стр. 1-10.
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T1 - Interaction of bulk nickel and nichrome with halogenated butanes

AU - Kenzhin, Roman M.

AU - Bauman, Yuri I.

AU - Volodin, Alexander M.

AU - Mishakov, Ilya V.

AU - Vedyagin, Aleksey A.

PY - 2017/9/26

Y1 - 2017/9/26

N2 - Catalytic chemical vapor deposition of halogenated butanes over bulk nickel-containing samples was studied. Butyl iodide and butyl bromide were used as substrates containing both hydrogen and halogen molecules. The experiments were performed in a flow reactor system as well as reaction under autogenic pressure at elevated temperature conditions. Scanning and transmission electron microscopies and ferromagnetic resonance spectroscopy were applied to examine the samples. The formation of structured particles of micron size was observed when nickel ribbon or nichrome wire was used as a bulk sample. The intermediates were shown to be stable in a narrow temperature range. The morphology of the resulting microcrystals was different depending on the metal precursor.

AB - Catalytic chemical vapor deposition of halogenated butanes over bulk nickel-containing samples was studied. Butyl iodide and butyl bromide were used as substrates containing both hydrogen and halogen molecules. The experiments were performed in a flow reactor system as well as reaction under autogenic pressure at elevated temperature conditions. Scanning and transmission electron microscopies and ferromagnetic resonance spectroscopy were applied to examine the samples. The formation of structured particles of micron size was observed when nickel ribbon or nichrome wire was used as a bulk sample. The intermediates were shown to be stable in a narrow temperature range. The morphology of the resulting microcrystals was different depending on the metal precursor.

KW - Ferromagnetic resonance

KW - Halogenated hydrocarbons

KW - Intermediates

KW - RAPET conditions

KW - Self-disintegration of bulk alloys

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