Indene polymerization under the action of titanium tetrachloride

E. I. Ionova, A. A. Lyapkov, V. G. Bondaletov, L. I. Bondaletova, T. V. Petrenko

Результат исследований: Материалы для журналаСтатья

2 Цитирования (Scopus)

Выдержка

The cationic polymerization of indene under the action of TiCl4 is considered, in the presence of toluene. The reaction is greatly affected by the competition between the solvent and the monomer in TiCl4 solvation. Active centers are formed on account of the direct addition of TiCl4 by the vinyl bond of the monomer. In the given system, polymerization is most likely due to chain growth at the contact pairs or solvationally separated ion pairs. Effective values of the rate constants of catalyst solvation and chain growth are calculated.

Язык оригиналаАнглийский
Страницы (с-по)496-500
Число страниц5
ЖурналCoke and Chemistry
Том52
Номер выпуска11
DOI
СостояниеОпубликовано - ноя 2009

Отпечаток

Solvation
polymerization
titanium
Titanium
Monomers
Polymerization
Cationic polymerization
toluene
Toluene
Rate constants
catalyst
Catalysts
ion
Ions
indene
titanium tetrachloride
rate

ASJC Scopus subject areas

  • Process Chemistry and Technology
  • Fuel Technology
  • Environmental Chemistry

Цитировать

Indene polymerization under the action of titanium tetrachloride. / Ionova, E. I.; Lyapkov, A. A.; Bondaletov, V. G.; Bondaletova, L. I.; Petrenko, T. V.

В: Coke and Chemistry, Том 52, № 11, 11.2009, стр. 496-500.

Результат исследований: Материалы для журналаСтатья

@article{a3c2f91145084455a40acdfb11859144,
title = "Indene polymerization under the action of titanium tetrachloride",
abstract = "The cationic polymerization of indene under the action of TiCl4 is considered, in the presence of toluene. The reaction is greatly affected by the competition between the solvent and the monomer in TiCl4 solvation. Active centers are formed on account of the direct addition of TiCl4 by the vinyl bond of the monomer. In the given system, polymerization is most likely due to chain growth at the contact pairs or solvationally separated ion pairs. Effective values of the rate constants of catalyst solvation and chain growth are calculated.",
author = "Ionova, {E. I.} and Lyapkov, {A. A.} and Bondaletov, {V. G.} and Bondaletova, {L. I.} and Petrenko, {T. V.}",
year = "2009",
month = "11",
doi = "10.3103/S1068364X09110076",
language = "English",
volume = "52",
pages = "496--500",
journal = "Coke and Chemistry",
issn = "1068-364X",
publisher = "Springer Verlag",
number = "11",

}

TY - JOUR

T1 - Indene polymerization under the action of titanium tetrachloride

AU - Ionova, E. I.

AU - Lyapkov, A. A.

AU - Bondaletov, V. G.

AU - Bondaletova, L. I.

AU - Petrenko, T. V.

PY - 2009/11

Y1 - 2009/11

N2 - The cationic polymerization of indene under the action of TiCl4 is considered, in the presence of toluene. The reaction is greatly affected by the competition between the solvent and the monomer in TiCl4 solvation. Active centers are formed on account of the direct addition of TiCl4 by the vinyl bond of the monomer. In the given system, polymerization is most likely due to chain growth at the contact pairs or solvationally separated ion pairs. Effective values of the rate constants of catalyst solvation and chain growth are calculated.

AB - The cationic polymerization of indene under the action of TiCl4 is considered, in the presence of toluene. The reaction is greatly affected by the competition between the solvent and the monomer in TiCl4 solvation. Active centers are formed on account of the direct addition of TiCl4 by the vinyl bond of the monomer. In the given system, polymerization is most likely due to chain growth at the contact pairs or solvationally separated ion pairs. Effective values of the rate constants of catalyst solvation and chain growth are calculated.

UR - http://www.scopus.com/inward/record.url?scp=78651552261&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78651552261&partnerID=8YFLogxK

U2 - 10.3103/S1068364X09110076

DO - 10.3103/S1068364X09110076

M3 - Article

AN - SCOPUS:78651552261

VL - 52

SP - 496

EP - 500

JO - Coke and Chemistry

JF - Coke and Chemistry

SN - 1068-364X

IS - 11

ER -