Hypoiodite-mediated metal-free catalytic aziridination of alkenes

Akira Yoshimura, Kyle R. Middleton, Chenjie Zhu, Victor N. Nemykin, Viktor V. Zhdankin

Результат исследований: Материалы для журналаСтатья

49 Цитирования (Scopus)

Выдержка

Look, no metal: A metal-free catalytic procedure for aziridination of alkenes using tetrabutylammonium iodide as the catalyst, m-chloroperoxybenzoic acid (mCPBA) as the terminal oxidant, and N-aminophthalimide as the nitrenium precursor has been developed (see scheme; right: X-ray structure of one of the products). Control experiments suggests that the active oxidant is in situ generated hypoiodous acid (HIO).

Язык оригиналаАнглийский
Страницы (с-по)8059-8062
Число страниц4
ЖурналAngewandte Chemie - International Edition
Том51
Номер выпуска32
DOI
СостояниеОпубликовано - 6 авг 2012
Опубликовано для внешнего пользованияДа

Отпечаток

Alkenes
Oxidants
Olefins
Metals
Acids
X rays
Catalysts
Experiments
hypoiodous acid
tetrabutylammonium
N-aminophthalimide

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Цитировать

Hypoiodite-mediated metal-free catalytic aziridination of alkenes. / Yoshimura, Akira; Middleton, Kyle R.; Zhu, Chenjie; Nemykin, Victor N.; Zhdankin, Viktor V.

В: Angewandte Chemie - International Edition, Том 51, № 32, 06.08.2012, стр. 8059-8062.

Результат исследований: Материалы для журналаСтатья

Yoshimura, Akira ; Middleton, Kyle R. ; Zhu, Chenjie ; Nemykin, Victor N. ; Zhdankin, Viktor V. / Hypoiodite-mediated metal-free catalytic aziridination of alkenes. В: Angewandte Chemie - International Edition. 2012 ; Том 51, № 32. стр. 8059-8062.
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