Highly efficient RuCl₃-catalyzed disproportionation of (diacetoxyiodo)benzene to iodylbenzene and iodobenzene; leading to the efficient oxidation of alcohols to carbonyl compounds

Mekhman S. Yusubov, Ki Whan Chi, Joo Yeon Park, Rashad Karimov, Viktor Vladimirovich Zhdankin

Исследовательская школа химических и биомедицинских технологий

Результат исследований: Материалы для журнала › Статья › рецензирование

Аннотация

(Diacetoxyiodo)benzene (DIB) selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl₃ (0.8-1.0 mol %) at room temperature in aqueous acetonitrile. This reaction proceeds via an initial instantaneous Ru-catalyzed disproportionation of DIB to iodobenzene and iodylbenzene with the latter acting as the actual stoichiometric oxidant toward alcohols.

Язык оригинала	Английский
Страницы (с-по)	6305-6308
Число страниц	4
Журнал	Tetrahedron Letters
Том	47
Номер выпуска	35
DOI	https://doi.org/10.1016/j.tetlet.2006.06.100
Состояние	Опубликовано - 28 авг 2006

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Доступ к документу

10.1016/j.tetlet.2006.06.100

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Highly efficient RuCl₃-catalyzed disproportionation of (diacetoxyiodo)benzene to iodylbenzene and iodobenzene; leading to the efficient oxidation of alcohols to carbonyl compounds. / Yusubov, Mekhman S.; Chi, Ki Whan; Park, Joo Yeon; Karimov, Rashad; Zhdankin, Viktor Vladimirovich.

В: Tetrahedron Letters, Том 47, № 35, 28.08.2006, стр. 6305-6308.

Результат исследований: Материалы для журнала › Статья › рецензирование

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abstract = "(Diacetoxyiodo)benzene (DIB) selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl3 (0.8-1.0 mol %) at room temperature in aqueous acetonitrile. This reaction proceeds via an initial instantaneous Ru-catalyzed disproportionation of DIB to iodobenzene and iodylbenzene with the latter acting as the actual stoichiometric oxidant toward alcohols.",

keywords = "(Diacetoxyiodo)benzene, Catalysis, Hypervalent iodine, Iodylbenzene, Oxidation",

author = "Yusubov, {Mekhman S.} and Chi, {Ki Whan} and Park, {Joo Yeon} and Rashad Karimov and Zhdankin, {Viktor Vladimirovich}",

year = "2006",

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T1 - Highly efficient RuCl3-catalyzed disproportionation of (diacetoxyiodo)benzene to iodylbenzene and iodobenzene; leading to the efficient oxidation of alcohols to carbonyl compounds

AU - Yusubov, Mekhman S.

AU - Chi, Ki Whan

AU - Park, Joo Yeon

AU - Karimov, Rashad

AU - Zhdankin, Viktor Vladimirovich

PY - 2006/8/28

Y1 - 2006/8/28

N2 - (Diacetoxyiodo)benzene (DIB) selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl3 (0.8-1.0 mol %) at room temperature in aqueous acetonitrile. This reaction proceeds via an initial instantaneous Ru-catalyzed disproportionation of DIB to iodobenzene and iodylbenzene with the latter acting as the actual stoichiometric oxidant toward alcohols.

AB - (Diacetoxyiodo)benzene (DIB) selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl3 (0.8-1.0 mol %) at room temperature in aqueous acetonitrile. This reaction proceeds via an initial instantaneous Ru-catalyzed disproportionation of DIB to iodobenzene and iodylbenzene with the latter acting as the actual stoichiometric oxidant toward alcohols.

KW - (Diacetoxyiodo)benzene

KW - Catalysis

KW - Hypervalent iodine

KW - Iodylbenzene

KW - Oxidation

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