High resolution study of the six lowest doubly excited vibrational states of PH2D

C. Leroy, O. N. Ulenikov, E. S. Bekhtereva, G. A. Onopenko, T. D. Chudinova

Результат исследований: Материалы для журналаСтатья

4 Цитирования (Scopus)

Выдержка

The five lowest doubly excited deformational vibrational bands ν 4 + ν6, 2ν6, ν3 + ν 4, ν3 + ν6, and 2ν3 of PH2D have been recorded for the first time using a Bruker 120 HR interferometer with a resolution 0.0033 cm-1 and analysed. Some transitions belonging to a very weak band 2ν4 have been also assigned. From the fit 24 and 86, respectively, diagonal and resonance interaction parameters were obtained which reproduce 1089 upper energy levels obtained from more than 4600 assigned transitions with the rms deviation of 0.00059 cm-1.

Язык оригиналаАнглийский
Страницы (с-по)228-237
Число страниц10
ЖурналJournal of Molecular Spectroscopy
Том234
Номер выпуска2
DOI
СостояниеОпубликовано - дек 2005

Отпечаток

Electron transitions
vibrational states
Interferometers
Electron energy levels
high resolution
interferometers
energy levels
deviation
interactions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Цитировать

High resolution study of the six lowest doubly excited vibrational states of PH2D. / Leroy, C.; Ulenikov, O. N.; Bekhtereva, E. S.; Onopenko, G. A.; Chudinova, T. D.

В: Journal of Molecular Spectroscopy, Том 234, № 2, 12.2005, стр. 228-237.

Результат исследований: Материалы для журналаСтатья

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abstract = "The five lowest doubly excited deformational vibrational bands ν 4 + ν6, 2ν6, ν3 + ν 4, ν3 + ν6, and 2ν3 of PH2D have been recorded for the first time using a Bruker 120 HR interferometer with a resolution 0.0033 cm-1 and analysed. Some transitions belonging to a very weak band 2ν4 have been also assigned. From the fit 24 and 86, respectively, diagonal and resonance interaction parameters were obtained which reproduce 1089 upper energy levels obtained from more than 4600 assigned transitions with the rms deviation of 0.00059 cm-1.",
keywords = "FTIR, High resolution, Infrared spectrum, PHD molecule, Spectroscopic parameters",
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AU - Leroy, C.

AU - Ulenikov, O. N.

AU - Bekhtereva, E. S.

AU - Onopenko, G. A.

AU - Chudinova, T. D.

PY - 2005/12

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N2 - The five lowest doubly excited deformational vibrational bands ν 4 + ν6, 2ν6, ν3 + ν 4, ν3 + ν6, and 2ν3 of PH2D have been recorded for the first time using a Bruker 120 HR interferometer with a resolution 0.0033 cm-1 and analysed. Some transitions belonging to a very weak band 2ν4 have been also assigned. From the fit 24 and 86, respectively, diagonal and resonance interaction parameters were obtained which reproduce 1089 upper energy levels obtained from more than 4600 assigned transitions with the rms deviation of 0.00059 cm-1.

AB - The five lowest doubly excited deformational vibrational bands ν 4 + ν6, 2ν6, ν3 + ν 4, ν3 + ν6, and 2ν3 of PH2D have been recorded for the first time using a Bruker 120 HR interferometer with a resolution 0.0033 cm-1 and analysed. Some transitions belonging to a very weak band 2ν4 have been also assigned. From the fit 24 and 86, respectively, diagonal and resonance interaction parameters were obtained which reproduce 1089 upper energy levels obtained from more than 4600 assigned transitions with the rms deviation of 0.00059 cm-1.

KW - FTIR

KW - High resolution

KW - Infrared spectrum

KW - PHD molecule

KW - Spectroscopic parameters

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