Выдержка
The second overtone band 3ν1 of sulfur dioxide has been studied for the first time with high resolution rotation-vibration spectroscopy. About 3000 transitions involving about 900 upper state energy levels with Jmax. = 66 and Kamax. = 24 have been assigned to the 3ν1 band. In the analysis, an effective Hamiltonian taking into account accidental interactions between the vibrational states (3 0 0), (2 2 0), and (0 4 1) was used. The Watson operator in A-reduction and Ir representation was used in the diagonal blocks of the Hamiltonian. As the result of analysis a set of parameters reproducing the initial experimental data with the rms = 0.00028 cm-1 was obtained.
| Язык оригинала | Английский |
|---|---|
| Страницы (с-по) | 111-121 |
| Число страниц | 11 |
| Журнал | Journal of Molecular Spectroscopy |
| Том | 255 |
| Номер выпуска | 2 |
| DOI | |
| Состояние | Опубликовано - 1 июн 2009 |
Отпечаток
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
Цитировать
High resolution study of the 3ν1 band of SO2. / Ulenikov, O. N.; Bekhtereva, E. S.; Horneman, V. M.; Alanko, S.; Gromova, O. V.
В: Journal of Molecular Spectroscopy, Том 255, № 2, 01.06.2009, стр. 111-121.Результат исследований: Материалы для журнала › Статья
}
TY - JOUR
T1 - High resolution study of the 3ν1 band of SO2
AU - Ulenikov, O. N.
AU - Bekhtereva, E. S.
AU - Horneman, V. M.
AU - Alanko, S.
AU - Gromova, O. V.
PY - 2009/6/1
Y1 - 2009/6/1
N2 - The second overtone band 3ν1 of sulfur dioxide has been studied for the first time with high resolution rotation-vibration spectroscopy. About 3000 transitions involving about 900 upper state energy levels with Jmax. = 66 and Kamax. = 24 have been assigned to the 3ν1 band. In the analysis, an effective Hamiltonian taking into account accidental interactions between the vibrational states (3 0 0), (2 2 0), and (0 4 1) was used. The Watson operator in A-reduction and Ir representation was used in the diagonal blocks of the Hamiltonian. As the result of analysis a set of parameters reproducing the initial experimental data with the rms = 0.00028 cm-1 was obtained.
AB - The second overtone band 3ν1 of sulfur dioxide has been studied for the first time with high resolution rotation-vibration spectroscopy. About 3000 transitions involving about 900 upper state energy levels with Jmax. = 66 and Kamax. = 24 have been assigned to the 3ν1 band. In the analysis, an effective Hamiltonian taking into account accidental interactions between the vibrational states (3 0 0), (2 2 0), and (0 4 1) was used. The Watson operator in A-reduction and Ir representation was used in the diagonal blocks of the Hamiltonian. As the result of analysis a set of parameters reproducing the initial experimental data with the rms = 0.00028 cm-1 was obtained.
KW - High-resolution spectra
KW - Spectroscopic parameters
KW - Sulfur dioxide
UR - http://www.scopus.com/inward/record.url?scp=67349175636&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=67349175636&partnerID=8YFLogxK
U2 - 10.1016/j.jms.2009.03.009
DO - 10.1016/j.jms.2009.03.009
M3 - Article
AN - SCOPUS:67349175636
VL - 255
SP - 111
EP - 121
JO - Journal of Molecular Spectroscopy
JF - Journal of Molecular Spectroscopy
SN - 0022-2852
IS - 2
ER -