High-resolution IR spectrum of AsH2D: Ro-vibrational analysis of the bending triad bands ν3, ν4, and ν6

O. N. Ulenikov, E. S. Bekhtereva, O. V. Gromova, T. D. Chudinova, W. Jerzembeck, H. Bürger

Результат исследований: Материалы для журналаСтатья

5 Цитирования (Scopus)

Аннотация

The infrared spectrum of the AsH2D molecule has been measured in the region of the three bending fundamental bands on a Fourier transform spectrometer with a resolution of 0.0024 cm-1 and analyzed for the first time. More than 7500 normally allowed and in addition about 600 forbidden, but perturbation-activated transitions with Jmax = 21, Kamax = 20 and Kcmax = 21 have been assigned to the bands ν3, ν4, and ν6. The measured transition wavenumbers were used to determine 1047 upper energy values. These energies were fitted with a Watson-type Hamiltonian in A reduction and IIIl representation taking into account resonance interactions between all three bending states, (001000), (000100), and (000001) and led to a physically meaningful set of 25 diagonal and 52 resonance spectroscopic parameters. These reproduce the experimental energies with an rms deviation of 0.00021 cm-1, which is close to the experimental uncertainty.

Язык оригиналаАнглийский
Страницы (с-по)114-122
Число страниц9
ЖурналJournal of Molecular Spectroscopy
Том251
Номер выпуска1-2
DOI
СостояниеОпубликовано - 1 сен 2008

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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