High resolution fourier transform spectrum of PD3 in the region of the stretching overtone bands 2v1 and v1 + v3

O. N. Ulenikov, Yu B. Yuhnik, E. S. Bekhtereva, N. E. Tyabaeva, H. Bürger, W. Jerzembeck, L. Fusina

Результат исследований: Материалы для журналаСтатья

5 Цитирования (Scopus)

Выдержка

The infrared spectrum of the PD3 molecule has been measured in the region of the first stretching overtone bands on a Fourier transform spectrometer with a resolution of 0.0068 cm-1 and analyzed for the first time. More than 800 transitions with Jmax = 15 have been assigned to the bands 2v1 and v1 + v3. An effective Hamiltonian was used which takes into account both the presence of resonance interactions between the states (2000) and (1010), and interactions of these with the third stretching vibrational state of the v = 2 polyad, (0020). A set of 44 spectroscopic parameters is obtained from the fit. This reproduces the 305 initial "experimental" upper rovibrational energies with an rms = 0.0015 cm-1.

Язык оригиналаАнглийский
Страницы (с-по)250-260
Число страниц11
ЖурналJournal of Molecular Spectroscopy
Том221
Номер выпуска2
DOI
СостояниеОпубликовано - 1 янв 2003

Отпечаток

Stretching
Fourier transforms
harmonics
Hamiltonians
high resolution
vibrational states
Spectrometers
infrared spectra
interactions
spectrometers
Infrared radiation
Molecules
molecules
energy

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

Цитировать

High resolution fourier transform spectrum of PD3 in the region of the stretching overtone bands 2v1 and v1 + v3. / Ulenikov, O. N.; Yuhnik, Yu B.; Bekhtereva, E. S.; Tyabaeva, N. E.; Bürger, H.; Jerzembeck, W.; Fusina, L.

В: Journal of Molecular Spectroscopy, Том 221, № 2, 01.01.2003, стр. 250-260.

Результат исследований: Материалы для журналаСтатья

Ulenikov, O. N. ; Yuhnik, Yu B. ; Bekhtereva, E. S. ; Tyabaeva, N. E. ; Bürger, H. ; Jerzembeck, W. ; Fusina, L. / High resolution fourier transform spectrum of PD3 in the region of the stretching overtone bands 2v1 and v1 + v3. В: Journal of Molecular Spectroscopy. 2003 ; Том 221, № 2. стр. 250-260.
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T1 - High resolution fourier transform spectrum of PD3 in the region of the stretching overtone bands 2v1 and v1 + v3

AU - Ulenikov, O. N.

AU - Yuhnik, Yu B.

AU - Bekhtereva, E. S.

AU - Tyabaeva, N. E.

AU - Bürger, H.

AU - Jerzembeck, W.

AU - Fusina, L.

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N2 - The infrared spectrum of the PD3 molecule has been measured in the region of the first stretching overtone bands on a Fourier transform spectrometer with a resolution of 0.0068 cm-1 and analyzed for the first time. More than 800 transitions with Jmax = 15 have been assigned to the bands 2v1 and v1 + v3. An effective Hamiltonian was used which takes into account both the presence of resonance interactions between the states (2000) and (1010), and interactions of these with the third stretching vibrational state of the v = 2 polyad, (0020). A set of 44 spectroscopic parameters is obtained from the fit. This reproduces the 305 initial "experimental" upper rovibrational energies with an rms = 0.0015 cm-1.

AB - The infrared spectrum of the PD3 molecule has been measured in the region of the first stretching overtone bands on a Fourier transform spectrometer with a resolution of 0.0068 cm-1 and analyzed for the first time. More than 800 transitions with Jmax = 15 have been assigned to the bands 2v1 and v1 + v3. An effective Hamiltonian was used which takes into account both the presence of resonance interactions between the states (2000) and (1010), and interactions of these with the third stretching vibrational state of the v = 2 polyad, (0020). A set of 44 spectroscopic parameters is obtained from the fit. This reproduces the 305 initial "experimental" upper rovibrational energies with an rms = 0.0015 cm-1.

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KW - Stretching overtones

KW - Vibration-rotation spectra

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