High-resolution Fourier transform spectrum of H2S in the region of the second hexade

O. N. Ulenikov, A. W. Liu, E. S. Bekhtereva, O. V. Gromova, L. Y. Hao, S. M. Hu

Результат исследований: Материалы для журналаСтатья

26 Цитирования (Scopus)

Аннотация

High-resolution Fourier transform infrared spectrum of H232S was recorded and analyzed in the region of the second hexade v=v1+12v2+v3=2.5. More than 1700 transitions were assigned to the 2ν1 + ν2, ν1 + ν2 + ν3, ν1 + 3ν2, 3ν2 + ν3, 5ν2, and ν2 + 2ν3 bands with the maximum value of quantum number J equal to 18, 18, 13, 11, 13, and 9, respectively. The theoretical analysis was fulfilled with a Hamiltonian model which takes into account numerous resonance interactions between all the vibrational states in this polyad. By a least-square fitting, finally 505 upper energy levels were reproduced by 80 parameters with an rms deviation of 0.0019 cm-1.

Язык оригиналаАнглийский
Страницы (с-по)270-278
Число страниц9
ЖурналJournal of Molecular Spectroscopy
Том234
Номер выпуска2
DOI
СостояниеОпубликовано - 1 дек 2005

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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