Halogenating and nitrating activity of reagents based on sodium nitrate and alkali metal halides in acetic acid

V. D. Filimonov, Yulia Yurievna Miroshnichenko, M. S. Yusubov, I. A. Perederina, Ki Whan Chi, O. Kh Poleshchuk

Результат исследований: Материалы для журналаСтатьярецензирование

5 Цитирования (Scopus)

Аннотация

Alkali metal halides NaF, KCl, and KBr sharply enhance the nitrating activity of sodium nitrate in acetic acid with respect to 9-methylcarbazole. In the presence of KI and KBr, both nitration and halogenation of the substrate occurs, while KCl and NaF promote only the nitration process. The results may be interpreted in terms of formation of the corresponding nitryl halides XNO2 (X = F, Cl, Br, I) whose structure and reactivity were examined in the framework of the density functional theory (DFT B3LYP/3-21G*).

Язык оригиналаАнглийский
Страницы (с-по)917-923
Число страниц7
ЖурналRussian Journal of Organic Chemistry
Том40
Номер выпуска7
DOI
СостояниеОпубликовано - 1 июл 2004

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Подробные сведения о темах исследования «Halogenating and nitrating activity of reagents based on sodium nitrate and alkali metal halides in acetic acid». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать