General and simple method for the synthesis of 3-nitroformazan using arenediazonium tosylates

Pavel Vasilievich Petunin, Rashid R. Valiev, Rodion G. Kalinin, Marina E. Trusova, Viktor Vladimirovich Zhdankin, Pavel S. Postnikov

Исследовательская школа химических и биомедицинских технологий

Результат исследований: Материалы для журнала › Статья › рецензирование

4 Цитирования (Scopus)

Аннотация

A general and simple procedure for the synthesis of 3-nitroformazan using arenediazonium tosylates was developed. This convenient procedure can be applied for the preparation of 3-nitroformazans containing electron-donating or electron-withdrawing groups. First the anomaly 1,5-bis(4-methoxyphenyl)-3-nitroformazan was synthesized as the mixture of TSSC (trans-syn, s-cis) and previously unknown for 3-nitroformazans TASC (transanti, s-cis) isomers. The structure and spectral characteristics of TASC isomer were explained using quantumchemical calculation with TDDFT/B3LYP/6-31++G(d,p) level of theory.

Язык оригинала	Английский
Страницы (с-по)	623-628
Число страниц	6
Журнал	Current Organic Synthesis
Том	13
Номер выпуска	4
Состояние	Опубликовано - 1 авг 2016

ASJC Scopus subject areas

Organic Chemistry
Biochemistry

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Цитировать

General and simple method for the synthesis of 3-nitroformazan using arenediazonium tosylates. / Petunin, Pavel Vasilievich ; Valiev, Rashid R.; Kalinin, Rodion G.; Trusova, Marina E.; Zhdankin, Viktor Vladimirovich ; Postnikov, Pavel S.

В: Current Organic Synthesis, Том 13, № 4, 01.08.2016, стр. 623-628.

Результат исследований: Материалы для журнала › Статья › рецензирование

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abstract = "A general and simple procedure for the synthesis of 3-nitroformazan using arenediazonium tosylates was developed. This convenient procedure can be applied for the preparation of 3-nitroformazans containing electron-donating or electron-withdrawing groups. First the anomaly 1,5-bis(4-methoxyphenyl)-3-nitroformazan was synthesized as the mixture of TSSC (trans-syn, s-cis) and previously unknown for 3-nitroformazans TASC (transanti, s-cis) isomers. The structure and spectral characteristics of TASC isomer were explained using quantumchemical calculation with TDDFT/B3LYP/6-31++G(d,p) level of theory.",

keywords = "Arenediazonium tosylates, Azo-coupling, Diazonium salts, Formazans, Quantum-chemical calculations, TDDFT",

author = "Petunin, {Pavel Vasilievich} and Valiev, {Rashid R.} and Kalinin, {Rodion G.} and Trusova, {Marina E.} and Zhdankin, {Viktor Vladimirovich} and Postnikov, {Pavel S.}",

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T1 - General and simple method for the synthesis of 3-nitroformazan using arenediazonium tosylates

AU - Petunin, Pavel Vasilievich

AU - Valiev, Rashid R.

AU - Kalinin, Rodion G.

AU - Trusova, Marina E.

AU - Zhdankin, Viktor Vladimirovich

AU - Postnikov, Pavel S.

PY - 2016/8/1

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AB - A general and simple procedure for the synthesis of 3-nitroformazan using arenediazonium tosylates was developed. This convenient procedure can be applied for the preparation of 3-nitroformazans containing electron-donating or electron-withdrawing groups. First the anomaly 1,5-bis(4-methoxyphenyl)-3-nitroformazan was synthesized as the mixture of TSSC (trans-syn, s-cis) and previously unknown for 3-nitroformazans TASC (transanti, s-cis) isomers. The structure and spectral characteristics of TASC isomer were explained using quantumchemical calculation with TDDFT/B3LYP/6-31++G(d,p) level of theory.

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