Gas-chromatographic separation of enantiomers of amino acid trimethylsilyl derivatives on a chelate-containing immobile phase

Yu G. Slizhov, M. A. Gavrilenko, A. G. Losev

Результат исследований: Материалы для журналаСтатья

Выдержка

The chromatographic properties of zirconium(IV) acetylacetonate with grafted L-arginine were studied. The thermodynamic parameters of the retention of enantiomers of trimethylsilyl derivatives of amino acids on this stationary phase were determined. It was shown that the energy difference of sorbate-sorbent complexation is high enough to separate racemic mixtures.

Язык оригиналаАнглийский
Страницы (с-по)305-306
Число страниц2
ЖурналRussian Journal of Physical Chemistry A
Том78
Номер выпуска2
СостояниеОпубликовано - фев 2004

Отпечаток

sorbates
Enantiomers
sorbents
enantiomers
Sorbents
Complexation
chelates
amino acids
Arginine
Gases
Thermodynamics
Derivatives
Amino Acids
thermodynamics
gases
energy
acetyl acetonate

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Цитировать

Gas-chromatographic separation of enantiomers of amino acid trimethylsilyl derivatives on a chelate-containing immobile phase. / Slizhov, Yu G.; Gavrilenko, M. A.; Losev, A. G.

В: Russian Journal of Physical Chemistry A, Том 78, № 2, 02.2004, стр. 305-306.

Результат исследований: Материалы для журналаСтатья

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