Formation of tin-tin oxide core–shell nanoparticles in the composite SnO2−x/nitrogen-doped carbon nanotubes by pulsed ion beam irradiation

P. M. Korusenko, S. N. Nesov, A. V. Bolotov, S. N. Povoroznyuk, A. I. Pushkarev, K. E. Ivlev, D. A. Smirnov

Результат исследований: Материалы для журналаСтатьярецензирование

14 Цитирования (Scopus)


The complex methods of transmission electron microscopy, energy dispersive X-ray analysis, and X-ray photoelectron spectroscopy were used to investigate the changes in the morphology, phase composition, and electronic structure of the composite SnO2−x/nitrogen-doped multiwalled carbon nanotubes (SnO2−x/N-MWCNTs) irradiated with the pulsed ion beam of nanosecond duration. The irradiation of the composite SnO2−x/N-MWCNTs leads to the formation of nanoparticles with the core–shell structure on the surface of CNTs with a sharp interfacial boundary. It has been established that the “core” is a metal tin (Sn0) with a typical size of 5–35 nm, and the “shell” is a thin amorphous layer (2–6 nm) consisting of nonstoichiometric tin oxide with a low oxygen content. The “core–shell” structure Sn[sbnd]SnOx is formed due to the process of heating and evaporation of SnO2−x under the effect of the ion beam, followed by vapor deposition on the surface of carbon nanotubes.

Язык оригиналаАнглийский
Страницы (с-по)37-43
Число страниц7
ЖурналNuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
СостояниеОпубликовано - 1 мар 2017

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Instrumentation

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