Formation and stabilization of gold clusters and nanoparticles in mordenites

A. Pestryakov, N. Bogdanchikova, I. Tuzovskaya, M. Avalos, M. H. Farías

Результат исследований: Материалы для книги/типы отчетовМатериалы для конференции

1 цитирование (Scopus)

Выдержка

Changes in electronic state of gold supported on mordenites during long-term storage in air have been studied by UV-visible spectroscopy method. Supporting gold on mordenites by ion-exchange method with further reduction with H2 led to formation of neutral and charged metal clusters and nanoparticles. Prolonged storage of the gold catalysts in air caused intensive redox processes. Ionic states of gold were partly reduced, perhaps, under the action of light, whereas metallic particles, in contrast, were oxidized by atmospheric oxygen. After one-year storage both as-prepared and reduced samples came to more or less similar stationary state. Cluster contribution and their stability depend strongly on acidity of zeolite (determined by SiO 2/Al2O3 molar ratio). Strong Brønsted acid sites favor the stabilization of gold clusters and their oxidation during prolonged storage in air because of higher redox potential of oxygen in acid media. Oxidation of gold clusters and nanoparticles can be considered as the main cause of gold catalyst deactivation during prolonged storage.

Язык оригиналаАнглийский
Название основной публикацииNanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
Страницы494-497
Число страниц4
Том1
СостояниеОпубликовано - 2010
СобытиеNanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010 - Anaheim, CA, Соединенные Штаты Америки
Продолжительность: 21 июн 201024 июн 2010

Другое

ДругоеNanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010
СтранаСоединенные Штаты Америки
ГородAnaheim, CA
Период21.6.1024.6.10

Отпечаток

Gold
Stabilization
stabilization
gold
Nanoparticles
nanoparticles
air
Air
Oxygen
Zeolites
catalysts
Oxidation
Catalyst deactivation
oxidation
acids
Acids
Electronic states
oxygen
metal clusters
Acidity

ASJC Scopus subject areas

  • Ceramics and Composites
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Цитировать

Pestryakov, A., Bogdanchikova, N., Tuzovskaya, I., Avalos, M., & Farías, M. H. (2010). Formation and stabilization of gold clusters and nanoparticles in mordenites. В Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010 (Том 1, стр. 494-497)

Formation and stabilization of gold clusters and nanoparticles in mordenites. / Pestryakov, A.; Bogdanchikova, N.; Tuzovskaya, I.; Avalos, M.; Farías, M. H.

Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Том 1 2010. стр. 494-497.

Результат исследований: Материалы для книги/типы отчетовМатериалы для конференции

Pestryakov, A, Bogdanchikova, N, Tuzovskaya, I, Avalos, M & Farías, MH 2010, Formation and stabilization of gold clusters and nanoparticles in mordenites. в Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. том. 1, стр. 494-497, Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010, Anaheim, CA, Соединенные Штаты Америки, 21.6.10.
Pestryakov A, Bogdanchikova N, Tuzovskaya I, Avalos M, Farías MH. Formation and stabilization of gold clusters and nanoparticles in mordenites. В Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Том 1. 2010. стр. 494-497
Pestryakov, A. ; Bogdanchikova, N. ; Tuzovskaya, I. ; Avalos, M. ; Farías, M. H. / Formation and stabilization of gold clusters and nanoparticles in mordenites. Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - Technical Proceedings of the 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010. Том 1 2010. стр. 494-497
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AU - Avalos, M.

AU - Farías, M. H.

PY - 2010

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N2 - Changes in electronic state of gold supported on mordenites during long-term storage in air have been studied by UV-visible spectroscopy method. Supporting gold on mordenites by ion-exchange method with further reduction with H2 led to formation of neutral and charged metal clusters and nanoparticles. Prolonged storage of the gold catalysts in air caused intensive redox processes. Ionic states of gold were partly reduced, perhaps, under the action of light, whereas metallic particles, in contrast, were oxidized by atmospheric oxygen. After one-year storage both as-prepared and reduced samples came to more or less similar stationary state. Cluster contribution and their stability depend strongly on acidity of zeolite (determined by SiO 2/Al2O3 molar ratio). Strong Brønsted acid sites favor the stabilization of gold clusters and their oxidation during prolonged storage in air because of higher redox potential of oxygen in acid media. Oxidation of gold clusters and nanoparticles can be considered as the main cause of gold catalyst deactivation during prolonged storage.

AB - Changes in electronic state of gold supported on mordenites during long-term storage in air have been studied by UV-visible spectroscopy method. Supporting gold on mordenites by ion-exchange method with further reduction with H2 led to formation of neutral and charged metal clusters and nanoparticles. Prolonged storage of the gold catalysts in air caused intensive redox processes. Ionic states of gold were partly reduced, perhaps, under the action of light, whereas metallic particles, in contrast, were oxidized by atmospheric oxygen. After one-year storage both as-prepared and reduced samples came to more or less similar stationary state. Cluster contribution and their stability depend strongly on acidity of zeolite (determined by SiO 2/Al2O3 molar ratio). Strong Brønsted acid sites favor the stabilization of gold clusters and their oxidation during prolonged storage in air because of higher redox potential of oxygen in acid media. Oxidation of gold clusters and nanoparticles can be considered as the main cause of gold catalyst deactivation during prolonged storage.

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