### Аннотация

The high resolution infrared spectra of hydrogen sulfide H_{2} ^{32}S were recorded with a Bruker IFS 125HR Fourier transform infrared spectrometer (Zürich prototype ZP2001) and analyzed in the region of 5650–6660 cm^{−1} where six interacting bands (2ν_{1}+ν_{2}, ν_{1}+ν_{2}+ν_{3}, ν_{1}+3ν_{2}, 3ν_{2}+ν_{3}, 5ν_{2} and ν_{2}+2ν_{3}) of the second hexade are located. 2452 transitions with maximum values of the quantum numbers J^{max} = 18/19/13/14/14/11 and K_{a} ^{max} = 10/11/8/11/7/5 were assigned in the experimental spectra to the 2ν_{1}+ν_{2}, ν_{1}+ν_{2}+ν_{3}, ν_{1}+3ν_{2}, 3ν_{2}+ν_{3}, 5ν_{2} and ν_{2}+2ν_{3} bands. On this basis, 194/216/108/104/90/9 upper ro–vibrational energies (more than 1.4 times higher number of both transitions and upper energy values compared to the preceding studies) were obtained for the upper vibrational states (210), (111), (130), (031), (050) and (012). These data were used in the weighted fit of the Watson Hamiltonian parameters. The 172 parameters obtained from the fit reproduce the 721 initial energy values of six vibrational states (2452 transitions) with the root mean square deviation d_{rms}=7.1×10^{−4} cm^{−1}. The 534 transitions belonging to the 2ν_{1}+ν_{2} and ν_{1}+ν_{2}+ν_{3} bands of H_{2} ^{34}S (197 upper energy values; about 1.5 times higher number for the ν_{1}+ν_{2}+ν_{3} band and more than two times higher number for the 2ν_{1}+ν_{2} band) were recorded and analysed. For the first time, 177 transitions (70 upper energy values) were assigned to the ν_{1}+ν_{2}+ν_{3} band of H_{2} ^{33}S.

Язык оригинала | Английский |
---|---|

Номер статьи | 106710 |

Журнал | Journal of Quantitative Spectroscopy and Radiative Transfer |

Том | 240 |

DOI | |

Состояние | Опубликовано - янв 2020 |

### ASJC Scopus subject areas

- Radiation
- Atomic and Molecular Physics, and Optics
- Spectroscopy

## Fingerprint Подробные сведения о темах исследования «Extended FTIR high resolution analysis of hydrogen sulfide in the region of the second hexad: Line positions and ro–vibrational energies of H<sub>2</sub> <sup>M</sup>S (M=32,33,34)». Вместе они формируют уникальный семантический отпечаток (fingerprint).

## Цитировать

_{2}

^{M}S (M=32,33,34).

*Journal of Quantitative Spectroscopy and Radiative Transfer*,

*240*, [106710]. https://doi.org/10.1016/j.jqsrt.2019.106710