Experimental and theoretical study of reactivity and structure of salicylic alcohols

M. L. Belyanin, E. V. Kulmeneva

Результат исследований: Материалы для книги/типы отчетовМатериалы для конференции

1 Цитирования (Scopus)

Аннотация

Calculations of spatial and electronic structures of salicylic alcohols and their acetates using quantum chemistry PM3 method were performed in approach of "isolated molecules" and in aqueous solutions. Calculations show that in approach of "isolated molecules" the most stable conformation is nonplanar as result of an internal hydrogen bond. On the other hand, into aqueous solutions salicylic alcohols exist mainly in form of an antiplanar conformations stabilized by internal hydrogen bonds. We have shown that reactivity of salicylic alcohols in the acylation reactions is controlled with latter conformations.

Язык оригиналаАнглийский
Название основной публикацииProceedings - KORUS 2000: 4th Korea-Russia International Symposium on Science and Technology
ИздательInstitute of Electrical and Electronics Engineers Inc.
Страницы227-230
Число страниц4
Том1
ISBN (печатное издание)0780364864, 9780780364868
DOI
СостояниеОпубликовано - 2000
Событие4th Korea-Russia International Symposium on Science and Technology, KORUS 2000 - Ulsan, Республика Корея
Продолжительность: 27 июн 20001 июл 2000

Другое

Другое4th Korea-Russia International Symposium on Science and Technology, KORUS 2000
СтранаРеспублика Корея
ГородUlsan
Период27.6.001.7.00

ASJC Scopus subject areas

  • Clinical Biochemistry
  • Computer Networks and Communications
  • Biotechnology
  • Civil and Structural Engineering
  • Mechanics of Materials
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Surfaces, Coatings and Films

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