Estimation of the thermodynamic probability of thermolysis reactions of humic and fulvic acids

A. V. Kravtsov, D. A. Bazhenov, L. I. Tarnovskaya, S. G. Maslov

Отделение химической инженерии

Результат исследований: Материалы для журнала › Статья › рецензирование

Аннотация

The changes in the amounts of the pseudocomponents of humic and fulvic acids in thermolysis are calculated on the basis of the results of NMR-13C, infrared spectroscopy, and functional analysis. The possible mechanism of transformation of the pseudocomponents in the course of thermal decomposition is considered. The thermodynamic probability of proceeding of the reactions is estimated. It is shown that among the selected 25 types of reactions, the proceeding of 21 of them is thermodynamically probable.

Язык оригинала	Английский
Страницы (с-по)	39-47
Число страниц	9
Журнал	Solid Fuel Chemistry
Том	32
Номер выпуска	1
Состояние	Опубликовано - 1998

ASJC Scopus subject areas

Chemical Engineering(all)
Chemistry(all)
Fuel Technology

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abstract = "The changes in the amounts of the pseudocomponents of humic and fulvic acids in thermolysis are calculated on the basis of the results of NMR-13C, infrared spectroscopy, and functional analysis. The possible mechanism of transformation of the pseudocomponents in the course of thermal decomposition is considered. The thermodynamic probability of proceeding of the reactions is estimated. It is shown that among the selected 25 types of reactions, the proceeding of 21 of them is thermodynamically probable.",

author = "Kravtsov, {A. V.} and Bazhenov, {D. A.} and Tarnovskaya, {L. I.} and Maslov, {S. G.}",

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AU - Maslov, S. G.

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AB - The changes in the amounts of the pseudocomponents of humic and fulvic acids in thermolysis are calculated on the basis of the results of NMR-13C, infrared spectroscopy, and functional analysis. The possible mechanism of transformation of the pseudocomponents in the course of thermal decomposition is considered. The thermodynamic probability of proceeding of the reactions is estimated. It is shown that among the selected 25 types of reactions, the proceeding of 21 of them is thermodynamically probable.

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