Electronic structure of bridging halogen atoms in metal halide dimers studied by the AMI method and NQR spectroscopy

O. Kh Poleshchuk, B. Nogaj, J. N. Latosińska, J. Koput

    Результат исследований: Материалы для журналаСтатьярецензирование

    Аннотация

    A nuclear quadrupole resonance (NQR) study of the electronic structure of bridging halogen atoms in dimers of transition and non-transition metal halides has been performed. An explanation of the differences in the NQR frequencies for transition and non-transition metal halides is proposed. The population of the bridging halogen atom orbitals and the metal-halogen bond lengths have been estimated by the AMI method. The aim of this paper was to obtain a relationship describing the lengths of the metal-halogen bonds.

    Язык оригиналаАнглийский
    Страницы (с-по)267-274
    Число страниц8
    ЖурналSolid State Nuclear Magnetic Resonance
    Том6
    Номер выпуска3
    DOI
    СостояниеОпубликовано - июн 1996

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Spectroscopy
    • Electronic, Optical and Magnetic Materials

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