TY - JOUR
T1 - Electronic structure of bridging halogen atoms in metal halide dimers studied by the AMI method and NQR spectroscopy
AU - Poleshchuk, O. Kh
AU - Nogaj, B.
AU - Latosińska, J. N.
AU - Koput, J.
PY - 1996/6
Y1 - 1996/6
N2 - A nuclear quadrupole resonance (NQR) study of the electronic structure of bridging halogen atoms in dimers of transition and non-transition metal halides has been performed. An explanation of the differences in the NQR frequencies for transition and non-transition metal halides is proposed. The population of the bridging halogen atom orbitals and the metal-halogen bond lengths have been estimated by the AMI method. The aim of this paper was to obtain a relationship describing the lengths of the metal-halogen bonds.
AB - A nuclear quadrupole resonance (NQR) study of the electronic structure of bridging halogen atoms in dimers of transition and non-transition metal halides has been performed. An explanation of the differences in the NQR frequencies for transition and non-transition metal halides is proposed. The population of the bridging halogen atom orbitals and the metal-halogen bond lengths have been estimated by the AMI method. The aim of this paper was to obtain a relationship describing the lengths of the metal-halogen bonds.
KW - AMI
KW - Bridging halogen atom
KW - Electronic structure
KW - Nuclear quadrupole resonance (NQR)
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U2 - 10.1016/0926-2040(96)01232-5
DO - 10.1016/0926-2040(96)01232-5
M3 - Article
C2 - 8863380
AN - SCOPUS:0030153317
VL - 6
SP - 267
EP - 274
JO - Solid State Nuclear Magnetic Resonance
JF - Solid State Nuclear Magnetic Resonance
SN - 0926-2040
IS - 3
ER -