Di-methyl carbonate transesterification with EtOH over MOFs: Basicity and synergic effect of basic and acid active sites

Luca Desidery, Somboon Chaemcheun, Mekhman Yusubov, Francis Verpoort

Результат исследований: Материалы для журналаСтатья

3 Цитирования (Scopus)

Выдержка

The catalytic activity of metal-organic frameworks (MOFs) towards the transesterification of dimethyl carbonate with ethanol has been unprecedented assessed. The relation between the catalytic activity and the amount of base active sites has been proved as well as the inability of the Lewis acid sites alone to catalyze this transesterification. The synergic effect of both acid and base sites cannot be completely excluded and a plausible reaction mechanism has been proposed. MOF-808 resulted to be more efficient than every heterogeneous commercial catalyst. MOF-808 can be recycled up to 4 times with exceptional retention of both catalytic activity and crystal structure.

Язык оригиналаАнглийский
Страницы (с-по)82-85
Число страниц4
ЖурналCatalysis Communications
Том104
DOI
СостояниеОпубликовано - 10 янв 2018

Отпечаток

Transesterification
Alkalinity
Carbonates
Catalyst activity
Metals
Acids
Lewis Acids
Ethanol
Crystal structure
Catalysts
methyl carbonate

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Process Chemistry and Technology

Цитировать

Di-methyl carbonate transesterification with EtOH over MOFs : Basicity and synergic effect of basic and acid active sites. / Desidery, Luca; Chaemcheun, Somboon; Yusubov, Mekhman; Verpoort, Francis.

В: Catalysis Communications, Том 104, 10.01.2018, стр. 82-85.

Результат исследований: Материалы для журналаСтатья

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AU - Verpoort, Francis

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KW - Ethyl methyl carbonate

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